The N-deficient porous g-C3N4 with broadband white light emission was constructed by supramolecular copolymerization design, which combined organic copolymers cyanuric acid and 2,4,6-triaminopyrimidine with melamine upon the mixture gas environment of (95%)­N2/(5%)­H2. Herein, we achieved great breakthrough in narrowing the band gap of g-C3N4 from 2.64 to 1.39 eV. Furthermore, in contrast to pristine g-C3N4, we demonstrated that the emission wavelengths of N-deficient porous g-C3N4 can be tuned from narrow blue to broadband white range, where the optimal white light coordinate position is (0.297, 0.345). The prepared N-deficient porous g-C3N4 overcomes the limitation of the narrow adjusting range of optical properties while using conventional g-C3N4 and makes it more promising for applications in solid-state displays.

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Fluorescence of negative‐charged nitrogen‐vacancy centers in nanodiamond allows applications in quantum metrology, nanoscale sensor, and bioimaging, of utmost relevance to domains from nanotechnologies to biosensing. However, the low color center content and collection efficiency of photons are crucial issues. Although, several studies about coupling nanodiamond into optical waveguides have already been proposed, the search for the most appropriate substance and simplest, most effective method are of keys. In this study, we present a novel nontraditional way to incorporate nanodiamond with increased negative‐charged nitrogen‐vacancy content to 75.48% into tellurite germanate glass. The hybrid glass is stable in structure with predominant TeO4 trigonal bipyramid. Moreover, the fluorescence intensity is enhanced in composite. Such robust nanodiamond in tellurite germanate glass optical system has the potential to be used for nanoparticle sensing and quantum metrology.

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