Based on experiments,
a numerical analysis is used to quantitatively
explore the influence of coal and surfactant microstructures on wettability.
First, based on an infrared spectrum experiment, the distribution
of oxygen-containing functional groups, aromatic hydrocarbons, and
aliphatic hydrocarbons of coal and surfactants was obtained. Second,
the wettability relationship between coal and different surfactants
was determined by optical titration, and the coal dust wettability
and surfaces were optimized. The key factors of the active agent wetting
ability affecting lignite wetting mainly depend on the carbonyl, ether,
and carboxyl groups in the surfactant. The factors affecting non-stick
coal and gas coal wetting mainly depend on the ether group and aromatic
amine in the surfactant. The factors affecting fat coal wetting mainly
depend on the ether group and hydroxyl group in the surfactant. Finally,
the factors affecting coking coal and anthracite wetting mainly depend
on the surfactant ether group, aliphatic amine, and aromatic amine.
Then, combining the structural parameters with the coal wetting results,
the quantitative mathematical relationship between coal dust wettability,
the important influencing factors of the surfactant, and the wettability
index was established. Finally, a perfect and reasonable wettability
evaluation model between coal and the surfactants was established.
The relative activity of methyl ether and aromatic ether is greater
than that of methyl ether, and the influence on the lignite, coking
coal, and anthracite wettability conforms to the model
. The influence on the non-caking coal and
fat coal wettability conforms to the model
, while the influence on the gas coal wettability
conforms to the model
Z
=
A
+
B
1
X
1
+
B
2
X
2
. In general, this study
provides scientific guidance for the compounding of high-efficiency
and environmentally protective composite dust suppressors to realize
clean mine production.
To investigate the zonal disintegration form of the surrounding rock in deep tunnels, model tests were performed in the simulation set-up of fracture mechanism and support technology of surrounding rock in deep tunnel. The test results illustrate that the first fracture of the surrounding rock occurred at the intersection of the tunnel floor and the side wall. After more serious destruction, the side wall and the vault were destroyed. Although the fracture width of each surrounding rock mass was distinct, they were relatively uniform with a nearly continuous fracture form. The width of the split bodies of the model tunnels (i.e., the annular zonal disintegration area) developed with an increasing load. It was observed from the fitting curves of the data that all radial strain values of the surrounding rock were more symmetric with a smooth fitting curve, and the maximum value occurred near the tunnel wall before reducing instantly. The circumferential strain values were dispersed and the data were inconsistent with the fitting curve, which caused some data to be unreliable. The phenomenon of zonal disintegration was primarily caused by radial tension strain of the surrounding rock. This phenomenon would not extend indefinitely as the rupture range would be limited to a certain extent, because the maximum radial tension strain of the surrounding rock was less than the limiting value.
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