The ferricrete deposit in Adi Kokeb district was investigated using field observations, petrographic studies and chemical analysis of samples for their geochemistry and mode of origin. Field observations confirmed the presence of kaolinites, thin iron bands and relict quartz veins. Petrographic studies of the samples revealed that quartz, sericite, muscovite, orthoclase feldspar and iron oxides/hydroxides are the dominant minerals. Geochemical determination of major, minor and trace elements of seventeen (17) samples were done using X-ray fluorescence (XRF). The results show a general increasing trend in Fe 2 O 3 (16.75-57.9 wt.%) and Al 2 O 3 (11.35-16.44 wt.%) values and decreasing trends in SiO 2 (57.05-22.01 wt.%) values from the Meta-sandstone to the ferricrete. The alkali and alkaline earth elements, notably K 2 O (0.142 wt.%), Na 2 O (<0.005 wt.%), CaO (0.075 wt.%) and MgO (0.098 wt.%), are highly depleted, confirming that iron precipitation with subsequent oxidation is major process in ferricrete formation. Similarly, the minor elements such as MnO (0.17 wt.%), TiO 2 (0.56 wt.%) and P 2 O 5 (0.154 wt.%) are highly depleted, implying their weak substitution for major elements in the ferricrete. The average value of trace elements such as Ba (669 ppm), Zr (348 ppm), Sr (215 ppm), Cu (125 ppm), Zn (55 ppm) and Pb (9.5 ppm) show a relative enrichment of the ferricrete compared to ferruginous sandstone and metasandstone. The relatively high concentrations of Zr, Ba and Sr in the ferricrete are attributed to their presence in detrital material during weathering (Zr) and their adsorption on neoformed kaolinite (Ba and Sr). Integration of field, petrographic and geochemical results suggest that the origin of this deposit is associated with weathering processes. Therefore, the deposit is likely to be a ferricrete.

Mineralogical and geochemical variations of elements from the Adi-Daero iron-duricrust were studied using petrographic, X-ray diffraction and geochemical analyses. Petrographic studies of the samples confirmed the presence of nodular and colloform textural features. The XRD analysis showed the presence of haematite, goethite, quartz, kaolinite and ilmenite are the mineral constituents. Major-element geochemistry was determined by ICP-AES, and trace and REEs were analysed using ICP-MS. Of the major oxides, Fe 2 O 3 (6.8-72.93 wt-%) and SiO 2 (11.07-77.75 wt-%) showed significant variation with generally increasing and decreasing trends from the iron-rich duricrust to the bedrock, respectively. In the profile studied, the alkali and alkaline earth elements (Ca, Mg, Na and K) were highly depleted, suggesting that iron-duricrust near-complete leaching. Elevated values of Sr and Ba in the lower part of the profile are probably due to their abundance in the protolith material (sandstone). A considerable enrichment of V and Cr, and Zr and REEs in the iron-rich duricrust and clay-rich horizon compared to the bedrock confirms their substitution for the Feoxyhydroxides, occurring in heavy mineral phases and adsorbed onto clay minerals, respectively. The La/Y <1 indicates an acidic environment in the upper part of the profile (AD-1 to AD-6; 0.64-0.99) and La/Y >1 a basic environment in the basal part of the profile (AD-7 to AD-12; 1.13-1.58). Similarly, the (La/Yb)N ratio of samples AD-1 to AD-6 (6.81-8.05) is significantly lower than that of AD-7 to , reflecting an acidic environment. Positive Ce anomalies in the samples of AD-1 to AD-2 (1.17-1.2) are linked to the existence of cerianite due to change in oxidation state of Ce while in AD-8 and AD-9 (0.92-0.93), it is related to adsorption of Ce ions onto clay particles protolith. Therefore, the absolute enrichment of iron in the Adi-Daero iron-duricrust deposit was most likely an in situ process that involved vertical transfer from the iron-poor sandstone source rock.