The mechanism and kinetics of the target components extraction from mineral raw materials (sulfur from sulfur ore by tetrachlorethylene, Al 2 O 3 from bauxite specs by NaOH, copper from ore and malachite by hydrochloric acid), as well as vegetable oils (from amaranth, amaranth hybrid and сamelina by organic solvents) have been studied. Experimental studies to confirm the diffusive nature of the target components extraction from mineral sources have been conducted. Diffusion coefficients for mineral samples have been obtained. It has been established that the target component extraction from the plant raw material occurs by the internal diffusion transfer of the component to the surface of the phase contact and the external diffusion from the surface to the liquid volume. Kinetic and diffusion coefficients for the samples of vegetable raw materials were determined.
The influence of the production conditions for rapeseed and soybean oils obtained by extraction in the system “solid – liquid” on the qualitative composition of the obtained vegetable oils has been studied. The main chemical values (acid value, iodine value, ester value, saponification value) and optical properties (refractometric refractive index and UV-Vis spectroscopy) for rapeseed and soybean oils obtained by extraction using methylene chloride as a solvent from different plant raw materials (grade of grinding is 0.2, 0.5 and 1.0 mm) and mixtures of crushed grain fractions have been determined. It has been shown that the grade of grinding of the raw material affects the quality of the obtained product.
The results of the research of extracting oil from sunflower seeds by the method of extraction are given. The kinetics and mechanism of the extraction process investigated. It is shown that the process of extracting sunflower seed oil is complicated and include as intra-diffusion and outer-diffusion oil transfer is similar to extraction of target components from other seeds of plant material (amaranth, rapeseed, etc.). The technique of experimental calculation of the diffusion coefficient is given and the slowest stage of the extraction process is determined, which determines the speed of the whole process. Кеуwordsextraction, plant raw materials, mechanism and kinetics of process.
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