Mechanical and vulcanization behaviors of styrene-butadiene rubber(SBR)/N330 and SBR/N330/PBMCN nanocomposites were investigated via partial replacement of SBR with pyrophyllite based modified composite nanopowder(PBMCN), which were prepared by melt mixing procedure. Results show a fairly good dispersion of PBMCN in the SBR/N330/PBMCN composites characterized by field-emission scanning electron microscope (FESEM). Mechanical and vulcanization behaviors of the as-abtained pruducts were measured according to GB/T 528-2009 and GB/T 16584-1996, respectively. Near properties in tensile strength, elongation at break and vulcanization behaviors were observed in SBR/N330/PBMCN nanocomposites when SBR was partially replaced by PBMCN for 8% mass fraction. A possible reinforcement mechanism of PBMCN to SBR/N330/PBMCN nanocomposites is also dicussed based on the experiment.
Long afterglow luminescent materials Sr2-xCaxMgSi2O7:Eu2+,Dy3+ (x=0-1.955)was synthesized by combustion method and characterized by X-ray diffraction,fluorescencespectrum and so on. Its preparing process conditions,the effect of Ca2+ replacing Sr2+ on its Luminescent performance were discussed. The results show it has a single phase and foamy structure,which is easy to be grinded into superfine powders. Its Luminescent property is importantly affected by water dosage(R= nH2O /nTEOS), reducer dosage (H=nreducer /nnitrate), gel grain dosage , gel grain size, arousing-burning temperature and burning time. Its best preparing process conditions are determined. A small quantity of Ca2+ replacing Sr2+ can raise its luminescence performance. Increasing Ca2+ content, its emission peak gradually wave to the long wave traverse, its luminous colors change from blue to yellow. Compared with the sample synthesized by high temperature solid reaction,the emission peaks of the sample synthesized by combustion method distinctly take place red shift.
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