With technological advancement, energy consumption and lack of energy supply are inevitable. Approximately 20% of total energy consumption is used for artificial light in standard office buildings. To reduce energy consumption for illumination purposes, a sunlight guiding panel was used to increase the amount of sunlight available indoors. However, in most designs of a sunlight guiding panel, the panel has to be placed on the outdoor surface of a window glass. This type of design is inconvenient for assembling and cleaning. To enhance the practicality of a sunlight guiding panel, we attempted to place the sunlight guiding panel on the indoor surface of a window glass. The simulation results revealed that when the sunlight guiding panel was placed on the indoor surface of a window glass, the aspect ratio of the light-guiding structure of the sunlight guiding panel had to be increased for guiding the sunlight from outdoors so as to increase the amount of sunlight indoors. To fabricate the proposed sunlight guiding panel, UV nanoimprint lithography was applied to pattern the light-guiding structure of the sunlight guiding panel. Moreover, a mold with a high-precision light-guiding structure was used in UV nanoimprint lithography. The mold was fabricated using ultraprecision machining technology. Both analytical and experimental investigations were conducted to confirm the proposed design. The average light-guiding efficiency was 89.9% with a solar elevation angle range of 35 • to 65 • , and the experimental results agreed well with the simulation results. This study elucidates light-guiding efficiency when the sunlight guiding panel is placed on the indoor surface of a window glass, which can increase the usage convenience and application potential of sunlight guiding panels. micromachining or nanomachining technique is required for manufacturing a sunlight guiding panel. Due to the difficulty in producing a sunlight guiding panel, a sunlight guiding panel has to be placed on the outdoor surface of a window glass in most designs of sunlight guiding panels [8,9]. This type of design is inconvenient for assembling and cleaning.