Photocathodic protection technology is emerging to harvest solar light for electrochemical corrosion protection of metals. Herein, ZnO/ZnSe/CdSe heterostructured nanowire arrays were synthesized on conductive glass substrates by a two-step ionexchange reaction in ZnO nanowire arrays. The as-prepared ZnO/ZnSe/CdSe core/shell nanostructure was unveiled by XRD, SEM, TEM, EDAX elemental mapping, and XPS analyses. The ZnO/ZnSe/CdSe ternary heterojunction photoanode exhibits a considerably enhanced absorption for visible light and a significantly increased separation, transfer, and collection efficiencies for photogenerated charges. When working as photoanodes, the as-deigned ZnO/ZnSe/CdSe heterostructured nanowire arrays demonstrates a superior photocathodic protection performance for the coupled 304 stainless steel under illumination with AM 1.5G. Results and DiscussionZnO/ZnSe/CdSe core/shell heterostructured nanowire array photoanodes were prepared on FTO substrates by sequential [a] Y.

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Nanocrystalline Bi2S3 shells were conformally deposited on ZnO nanowire arrays via a successive ionic layer adsorption and reaction approach. Microstructure, optical, and electric properties of the as-prepared ZnO/Bi2S3 core/shell nanowire heterostructures were thoroughly investigated using various characterization and electrochemical methods. Compared with the pristine ZnO photoanode (−734 mV and 0.57 mA·cm−2), the ZnO/Bi2S3 photoanode with a type-II heterojunction exhibited a more negative shift in the coupled open circuit potential (−862 mV) and a higher photocurrent density (2.92 mA·cm−2), achieving more effective photocathodic protections for the coupled 304 stainless steel under solar illumination.