Inhomogeneous structures with carbon nanotubes (CNTs), reinforced with Cu composite foams as the reinforcing skeletons (CNTs/Cuf®Cu), have been designed to overcome the paradox between strength and ductility or conductivity in copper matrix composites. The interface between CNTs and the copper matrix is usually weak, due to poor wettability and interaction. In this study, nickel nanoparticles are decorated onto CNTs to improve interfacial bonding. The broader interface transition area between CNTs and copper with Ni3C interfacial products formed, and a combination of improved electrical conductivity (95.6% IACS), tensile strength (364.9 MPa), and elongation (40.6%) was achieved for the Ni-decorated CNTs/Cuf®Cu (Ni-CNTs/Cuf®Cu). In addition, the strengthening mechanisms are discussed in this study.
The ladle nozzle is one of the most important components in metal smelting. The cracking phenomenon occurs due to excessive thermal stress, which seriously affects the performance and life of the ladle nozzle. In this paper, a new composite structure of ladle nozzle is proposed, which consists of two materials with different properties and costs. The thermal physical parameters of the material are measured by high temperature dynamic Young's modulus test method, thermal expansion test and flashing method. Based on the new structural model of the composite ladle nozzle, finite element simulation is used to combine the material ontology model, contact mechanics model and heat transfer model to study the temperature and thermal stress distribution inside the composite structure of the ladle nozzle during the casting process by taking representative key points inside the ladle nozzle. There is a large temperature gradient in the area near the casting hole, and the farther away from the casting hole, the smaller the temperature change. The ladle nozzle structure was optimized and compared with the existing ladle nozzle structure. The results show that the optimized composite structure of the ladle nozzle has significantly lowered thermal stress extremes under thermal shock, while the thermal stress distribution tends to be more uniform, which can largely reduce the chance of crack generation. This study is of great significance for improving the reliability and service life of the ladle nozzle and reducing its production cost.
The heat released from an aluminum−air battery has a great effect on its performance and operating life during the discharge process. A theoretical model was proposed to evaluate the resulting thermal effect, and the generated heat was divided into the following sources: anodic aluminum oxidation reaction, cathodic oxygen reduction reaction, heat production against the battery internal resistance, and hydrogen-evolution reaction. Quantitative analysis was conducted on each part, showing that all heat production sources increased with discharge current density. It should be noted that the heat caused by hydrogen evolution accounted for the most, up to 90%. Furthermore, the regulation strategy for inhibiting hydrogen evolution was developed by addition of hybrid additives to the electrolyte, and the hydrogen-evolution rate was greatly reduced by more than 50% as was the generated heat. This research has important guidance for the thermal effect analysis of aluminum–air batteries, together with control of the thermal management process by inhibiting hydrogen evolution, thus promoting their practical application.
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