CCS, Carbon Capture and Storage, is considered a promising technology to abate CO2 emissions from point sources. The present review deals with the principle of postcombustion capture techniques, including thermal or pressure swing principles, adsorption or absorption, and electrical swing or membrane separation processes.Opportunities and challenges are assessed. In the first section of absorption processes, several commercial technologies are compared, and complemented by the aqueous or chilled ammonia (NH3) process, and a dual or strong alkali absorption. The second section deals with adsorption where fixed beds, circulating fluidized beds and countercurrent bed configurations will be discussed, with special focus on the different adsorbents ranging from zeolites or activated carbon, to more complex aminefunctionalized adsorbents, nanotubes or metal organic frameworks (MOFs), and alkali-
The worldwide production of polymeric foam materials is growing due to their advantageous properties of light weight, high thermal insulation, good strength, resistance and rigidity. Society creates ever increasing amounts of poly-urethane (PU) waste. A major part of this waste can be recycled or recovered in order to be put into further use. The PU industry is committed to assist and play its part in the process. The recycling and recovery of PU foam cover a range of mechanical, physical, chemical and thermo-chemical processes. In addition to the welldocumented mechanical and chemical processing options, thermo-chemical treatments are important either as ultimate disposal (incineration) or towards feedstock recovery, leading to different products according to the thermal conditions of the treatment. The review focuses on these thermo-chemical and thermal processes. As far as pyrolysis is concerned, TDI and mostly polyol can be recovered. The highest recovery yields of TDI and polyols occur at low temperatures (150-200 • C). It is however clear from literature that pure feedstock will not be produced, and that a further upgrading of the condensate will be needed, together with a thermal or alternative treatment of the non-condensables. Gasification towards syngas has been studied on a larger and industrial scale. Its application would need the location of the PU treatment plant close to a chemical plant, if the syngas is to be valorized or considered in conjunction with a gas-fired CHP plant. Incineration has been studied mostly in a cofiring scheme. Potentially toxic emissions from PU combustion can be catered for by the common flue gas cleaning behind the incineration itself, making this solution less evident as a stand-alone option: the combination with other wastes (such as municipal solid waste) in MSWI ′ s seems the indicated route to go.
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