The increase of carbon dioxide (CO2) in the atmosphere has resulted in a global greenhouse effect and extreme weather. Photocatalytic conversion of CO2 into valuable chemicals driven by solar energy is conceivable for solving the above problem. Metal–organic frameworks (MOFs) as a class of organic–inorganic hybrid materials have considerable prospect for carbon dioxide reduction reaction (CO2RR) photocatalysis. Nevertheless, most MOFs in the CO2RR still have limited photocatalytic performance as well as selectivity caused by having a single metal and face the challenge of instability. Herein, 10 Prussian blue analogues (PBAs) as heterogeneous catalysts were directly employed for the photocatalytic CO2RR, which exhibit good photocatalytic performance for CO production. A mass evolution rate of 140 mmol g–1 h–1, an apparent quantum efficiency (AQY) of about 0.7%, and a selectivity of about 96.8% for CO were obtained over Ni–Co PBA. Notably, the CO2RR activities of MIICo PBAs are better than those of MII–Fe PBAs, but the former’s selectivities for CO are lower than those of the latter. The divergence of activity is dependent on their electron transfer rates, which is confirmed by the electrochemical experiments and spectral characterization. In addition, density functional theory (DFT) as well as H2 adsorption and desorption experiments of the PBAs reveal the difference in selectivity.

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Abstract:In the presence of a catalytic amount of PdCl 2 A C H T U N G T R E N N U N G (PPh 3 ) 2 and a silylating agent, organozinc halides reacted with carbonyl compounds to give the corresponding (E)-stilbenes in good to excellent yields under mild conditions. The reaction mechanism is briefly discussed.

In this study, a facile CuI catalyzed synthesis of sulfones involving a nucleophilic addition of functionalized organozinc reagents to organic sulfonyl chlorides is realized. This reaction proceeds efficiently at room temperature, giving rise to various functional group substituted sulfones, generally in moderate to high yields. The method provides a novel, simple, and promising strategy for functionalized sulfone synthesis in the research field of sulfur chemistry.