A reaction-diffusion population model with a general time-delayed growth rate per capita is considered. The growth rate per capita can be logistic or weak Allee effect type. From a careful analysis of the characteristic equation, the stability of the positive steady state solution and the existence of forward Hopf bifurcation from the positive steady state solution are obtained via the implicit function theorem, where the time delay is used as the bifurcation parameter. The general results are applied to a "food-limited" population model with diffusion and delay effects as well as a weak Allee effect population model.
A diffusive logistic equation with mixed delayed and instantaneous density dependence and Dirichlet boundary condition is considered. The stability of the unique positive steady state solution and the occurrence of Hopf bifurcation from this positive steady state solution are obtained by a detailed analysis of the characteristic equation. The direction of the Hopf bifurcation and the stability of the bifurcating periodic orbits are derived by the center manifold theory and normal form method. In particular, the global continuation of the Hopf bifurcation branches are investigated with a careful estimate of the bounds and periods of the periodic orbits, and the existence of multiple periodic orbits are shown.
An improved practical method for the photodriven diimide reduction of olefins was investigated. This catalyst‐free procedure proceeds at ambient temperature, utilizes air as oxidant and a lower hydrazine loading, and produces inert nitrogen gas as the sole byproduct. Several functional groups were tolerated, and in some cases, the reaction was chemoselective. Challenging substrates such as cinnamate ester derivatives and trans‐stilbene were reduced in excellent yields. The small amount of UVA rays emitted from a household compact fluorescent light bulb was proposed to enable the cis/trans isomerization of the diimide and to promote the loss of hydrogen from the diimide.
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