Visible-light-driven conversion of CO into chemical fuels is an intriguing approach to address the energy and environmental challenges. In principle, light harvesting and catalytic reactions can be both optimized by combining the merits of homogeneous and heterogeneous photocatalysts; however, the efficiency of charge transfer between light absorbers and catalytic sites is often too low to limit the overall photocatalytic performance. In this communication, it is reported that the single-atom Co sites coordinated on the partially oxidized graphene nanosheets can serve as a highly active and durable heterogeneous catalyst for CO conversion, wherein the graphene bridges homogeneous light absorbers with single-atom catalytic sites for the efficient transfer of photoexcited electrons. As a result, the turnover number for CO production reaches a high value of 678 with an unprecedented turnover frequency of 3.77 min , superior to those obtained with the state-of-the-art heterogeneous photocatalysts. This work provides fresh insights into the design of catalytic sites toward photocatalytic CO conversion from the angle of single-atom catalysis and highlights the role of charge kinetics in bridging the gap between heterogeneous and homogeneous photocatalysts.
Scholars are directing more attention to employee perceptions of human resources (HR) practices and have explored issues such as whether and how employees' idiosyncratic or collective perceptions of HR practices shape employee outcomes. To further this area of research, we seek to determine what authors mean when they refer to "employee perceptions of HR practices". We review 105 articles from leading human resource management journals and find that employee perceptions of HR practices is not a monolithic concept. Rather, following previous scholars, we identify three distinct components of employee perceptions of HR practices: the 'what', 'how', and 'why'. We critically summarize extant literature on these three components of employee HR perception and propose future research directions, including enriching the theoretical foundations of HR communication, embracing cross-national contexts, and enhancing practical relevance. KEYWORDS Employee human resource perceptions; perceived human resource strength; human resource attributions Over the last decade, the strategic human resource management field has paid increasing attention to employee perceptions of human resource (HR) practices (Beijer, Peccie,
Identifying
the catalytically active site(s) in the oxygen reduction
reaction (ORR), under real-time electrochemical conditions, is critical
to the development of fuel cells and other technologies. We have employed in situ synchrotron-based X-ray absorption spectroscopy
(XAS) to investigate the synergistic interaction of a Co–Mn
oxide catalyst which exhibits impressive ORR activity in alkaline
fuel cells. X-ray absorption near edge structure (XANES) was used
to track the dynamic structural changes of Co and Mn under both steady
state (constant applied potential) and nonsteady state (potentiodynamic
cyclic voltammetry, CV). Under steady state conditions, both Mn and
Co valences decreased at lower potentials, indicating the conversion
from Mn(III,IV) and Co(III) to Mn(II,III) and Co(II), respectively.
Rapid X-ray data acquisition, combined with a slow sweep rate in CV,
enabled a 3 mV resolution in the applied potential, approaching a
nonsteady (potentiodynamic) state. Changes in the Co and Mn valence
states were simultaneous and exhibited periodic patterns that tracked
the cyclic potential sweeps. To the best of our knowledge, this represents
the first study, using in situ XAS, to resolve the
synergistic catalytic mechanism of a bimetallic oxide. Strategies
developed/described herein can provide a promising approach to unveil
the reaction mechanism for other multimetallic electrocatalysts.
Technology has changed the way we work and how companies manage their employees. This article reviews 60 years of research on the relationship between technology and human resource management, as represented in Human Resource Management. Based on 154 articles, we identify recurring and evolving patterns of research on technology across three time periods (separated by the advent of the personal computer in 1977 and by the popularization of consumer internet services in 1997), three perspectives on technology (tool, proxy, and ensemble view of technology), and three thematic streams (the impact of technology on jobs and organizations, the utilization of technology in HR activities, and the management of technology workers). Drawing on patterns of research that emerged in the past, we provide suggestions for future HR research on newly arriving technology.
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