The emission from transition metal complexes is usually produced from triplet excited states. Owing to strong spin-orbit coupling (SOC), the fast conversion of singlet to triplet excited states via intersystem crossing (ISC) is facilitated. Hence, in transition metal complexes, emission from singlet excited states is not favoured. Nevertheless, a number of examples of transition metal complexes that fluoresce with high intensity have been found and some of them were even comprehensively studied. In general, three common photophysical characteristics are used for the identification of fluorescent emission from a transition metal complex: emission lifetimes on the nanosecond scale; a small Stokes shift; and intense emission under aerated conditions. For most of the complexes reviewed here, singlet emission is the result of ligand-based fluorescence, which is the dominant emission process due to poor metal-ligand interactions leading to a small metal contribution in the excited states, and a competitive fluorescence rate constant when compared to the ISC rate constant. In addition to the pure fluorescence from metal complexes, another two types of fluorescent emissions were also reviewed, namely, delayed fluorescence and fluorescence-phosphorescence dual emissions. Both emissions also have their respective unique characteristics, and thus they are discussed in this perspective.

Chalcone related compounds have been reported as a poor luminescence molecule due to the quenching processes from the intramolecular torsional motions andcis-transisomerization in theα,β-unsaturated ketone moiety. Despite this limitation, we found a way to improve the luminescent efficiency of our bis-chalcone derivative. In this project, two series of bis-chalcone compounds have been synthesized through Claisen-Schmidt condensation by reacting terephthaldehyde or 2,5-dimethoxyterephthaldehyde with the respective R-acetophenone [where R = H (1aand2a) andortho-hydroxy (1band2b)] in 1 : 2 mole ratio. The presence of a methoxy (OMe) substituent on the central phenyl ring of bis-chalcone has weakened the C=C bond at theα,β-unsaturated ketone moiety of2aand2b. Interestingly, the OMe group has improved the emission efficiency of the bis-chalcone; that is, the quantum yield of1ain DCM solution was not able to be determined due to poor luminescence, but the quantum yield of2ain DCM solution was improved to 0.57. In addition, compound2aalso shows solvatochromism effect where theλmaxemission shifted from 499 nm in nonpolar solvents (benzene) to 523 nm in polar solvents (acetonitrile). This work provides another way to improve the emission efficiency of chalcone related compounds apart from using the complexation method which has been reported before.

The present paper reports the use of 31P NMR spectroscopy to predict the isomer structures of [bis{4-methoxy-phenyl-[3-(4-methoxy-phenyl)-allylidene]-amino}]-bis[triphenylphosphine]ruthenium(II), also known as bis{(di-p-anisole)-1,4-azabutadiene}-bis[triphenylphosphine]ruthenium(II), complexes. The complexation reaction was carried out under refluxing condition of (di-p-anisole)-1,4-azabutadiene (compound 1), triphenylphosphine (PPh3), and ruthenium chloride in the ratio of 2 : 2 : 1 for five hours. In addition, ruthenium(II) complexes were also characterized using FTIR and UV-Vis spectroscopy to support the formation of ruthenium(II) complexes. 31P NMR spectroscopic study on ruthenium(II) complexes suggested that there are three isomers present after the complexation reaction and all the ruthenium complexes demonstrate octahedral geometry.

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Ru(II) complexes with diazabutadiene (R-DAB) ligands have been prepared. The reaction of RuCl 3 •nH 2 O with P(p-tolyl) 3 gave a [RuCl 2 {P(p-tolyl) 3 }] precursor, whose reactions with R-DAB in toluene gave dinuclear trichloro-bridged Ru(II) complexes [Ru 2 Cl 3 (P(p-tolyl) 3 ) 2 (R-DAB) 2 ](BF 4 ) which have been characterized by spectroscopic methods. In addition, one of the complexes was characterized using X-ray crystallography. Meanwhile, two mononuclear Ru(II) complexes [RuCl 2 (P(p-tolyl) 3 ) 2 (R-DAB)] were obtained from the reactions of the [RuCl 2 {P(p-tolyl) 3 }] precursor with R-DAB ligands in THF. The two trans-mononuclear complexes were characterized by X-ray crystallography and solid-state 31 P NMR. A temperature-dependent 31 P NMR study was carried out to monitor the formation of dinuclear and mononuclear complexes.