Harvesting biobased epoxy resins
with improved thermomechanical
properties (e.g., glass transition temperature T
g and storage modulus), mechanical and dielectric similar and
even superior to that of bisphenol A epoxy resin (DGEBA) is vital
to many applications, yet remains a substantial challenge. Here we
develop a novel eugenol-based epoxy monomer (TEU-EP) with a branched
topology and a very rich biobased retention (80 wt %). TEU-EP can
be well cured by 3,3′-diaminodiphenyl sulfone (33DDS) and the
resultant TEU-EP/33DDS system can be considered as a “single”
epoxy component, exhibiting adequate reactivity at high processing
temperatures. Importantly, compared with DGEBA/33DDS, TEU-EP/33DDS
achieves a 33 °C, 39% and 55% increment in the glass transition
temperature, Young’s modulus, and hardness, respectively, and
shows the improved creep resistance and dimensional stability. TEU-EP/33DDS
is also characterized by the considerably reduced permittivity, dielectric
loss factor, and flammability with high yield of pyrolytic residual.
Overall, TEU-EP endows the cured epoxy with a number of the distinguished
properties outperforming its DGEBA counterpart, and therefore may
find practical applications in demanding and even cutting-edge areas.
The rainfall erosivity factor (R) represents the multiplication of rainfall energy and maximum 30 minutes intensity by event (EI 30) and year. This rainfall erosivity index is widely used for empirical soil loss prediction. Its calculation, however, requires high temporal resolution rainfall data that are not readily available in many parts of the world. The purpose of this study was to parameterize models suitable for estimating erosivity from daily rainfall data, which are more widely available. One-minute resolution rainfall data recorded in sixteen stations over the eastern water erosion impacted regions of China were analyzed. The R-factor ranged from 781.9 to 8258.5 MJ mm ha-1 h-1 y-1. A total of 5942 erosive events from one-minute resolution rainfall data of ten stations were used to parameterize three models, and 4949 erosive events from the other six stations were used for validation. A threshold of daily rainfall between days classified as erosive and non-erosive was suggested to be 9.7 mm based on these data. Two of the models (I and II) used power law functions that required only daily rainfall totals. Model I used different model coefficients in the cool season (Oct.-Apr..) and warm season (May-Sept.), and Model II was fitted with a sinusoidal
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