No abstract

Superhydrophobic metallic materials have drawn broad research interest because of promising applications in various fields. The mechanical stability of superhydrophobic surfaces is currently a major concern limiting their practical applications. Herein, we developed a simple method to fabricate robust superhydrophobic surfaces on stainless steel via direct ultrafast laser microprocessing. Of note is that the fabricated superhydrophobic surfaces can withstand mechanical abrasion against an 800 grit SiC sandpaper for 2.3 m at an applied pressure of 5.5 kPa without losing superhydrophobicity. It is proposed that the robust superhydrophobicity may be attributable to the formation of unique hierarchical micro-/nanostructures and a nonpolar carbon layer on the surface. The hierarchical structures are composed of laser-created micropillars and ablation-induced nanoparticles. The fabricated surfaces exhibit good thermal stability and still show superhydrophobicity after thermal treatment at 100 °C for 120 min, which is related to the inorganic nature of metallic materials. An excellent anti-icing property is achieved on the fabricated surfaces with the water droplets on it retaining the liquid state for over 500 min at −8.5 ± 0.5 °C, which benefits from the obtained superhydrophobicity, based on classic nucleation theory and the heat transfer between the rough solid surface and water droplet. We envision that the presented method provides a facile and effective route to fabricate large-area superhydrophobic surfaces with robust mechanical stability and excellent anti-icing property.

High corrosion rate in physiological environment of the body is the major drawback of magnesium alloys for their successful applications as biodegradable orthopaedic implants. In the present study, corrosion behaviour of AZ91D magnesium alloy after laser surface melting (LSM) was studied in modified-simulated body fluid at 37°C. The improved corrosion resistance of AZ91D alloy using LSM was found to depend on the solidification microstructure in the laser-melted zone. The general and pitting corrosion resistance of laser-treated surface was significantly enhanced due to the refined continuous network of b-Mg 17 Al 12 phases and the increased Al concentration in the laser-melted zone.

Porous structure of reduced graphene oxide (rGO) plays an important role in developing flexible graphene-based devices. In this work, we report a novel methodology for reduction of freestanding graphite oxide (GO) sheet by picosecond pulse laser direct writing in liquid nitrogen. Non-agglomerate and porous structure of rGO is fabricated successfully due to frozen effect during laser processing. Compared with laser-irradiated rGO developed in N2 gas at ambient environment, the frozen rGO developed in liquid N2 shows better ordered structure with less defects, crack-free morphology as well as better electron supercapacitor performance including 50–60 Ω/sq in sheet electrical resistance. Mechanism of cryotemperature photoreduction GO is also discussed.