Graphene oxide obtained by the Hummers method was discovered to be an efficient and recyclable acid catalyst for the conversion of fructose-based biopolymers into 5-ethoxymethylfurfural (EMF). EMF yields of 92%, 71%, 34% and 66% were achieved when 5-hydroxymethylfurfural (HMF), fructose, sucrose and inulin were used as starting materials, respectively.
An efficient strategy is developed
for chemical recycling of cured
epoxy resin (CEP) from its carbon fiber reinforced polymer composites
(CFREP) using AlCl3/CH3COOH as the degradation
system. Acetic acid swells the dense structures of CEP, facilitating
the penetration of the aluminum ion catalyst into the polymer matrix.
The weakly coordinating aluminum ions in CH3COOH solution
selectively cleave the C–N bond while leaving the C–C,
C–O (aryl alkyl ether) bonds intact. This process recovers
valuable oligomers and carbon fibers from CFREP.
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