Asphaltenes are known to cause severe flow assurance problems in the near-wellbore region of oil reservoirs. Understanding the mechanism of asphaltene deposition in porous media is of great significance for the development of accurate numerical simulators and effective chemical remediation treatments. Here, we present a study of the dynamics of asphaltene deposition in porous media using microfluidic devices. A model oil containing 5 wt % dissolved asphaltenes was mixed with n-heptane, a known asphaltene precipitant, and flowed through a representative porous media microfluidic chip. Asphaltene deposition was recorded and analyzed as a function of solubility, which was directly correlated to particle size and Péclet number. In particular, pore-scale visualization and velocity profiles, as well as three stages of deposition, were identified and examined to determine the important convection-diffusion effects on deposition.
Precise dispensing of microdroplets is an important process for droplet-based microfluidics. The dropletformation by shear force between two immiscible fluids depends on their flow rates, the viscosities, and the interfacial tension. In this letter, the authors report the use of integrated microheater and temperature sensor for controlling the dropletformation process. The technique exploits the dependency on temperature of viscosities and interfacial tension. Using a relatively low heating temperature ranging from 25to70°C, the droplet diameter can be adjusted to over two times of its original value. The relatively low temperature range makes sure that this concept is applicable for droplets containing biological samples
Asphaltenes are components in crude oil known to deposit and interrupt flows in critical regions during oil production, such as the wellbore and transportation pipelines. Chemical dispersants are commonly used to disperse asphaltenes into smaller agglomerates or increase asphaltene stability in solution with the goal of preventing deposition. However, in many cases, these chemical dispersants fail in the field or even worsen the deposition problems in the wellbores. Further understanding of the mechanisms by which dispersants alter asphaltene deposition under dynamic flowing conditions are needed to better understand flow assurance problems. Here, we describe the use of porous media microfluidic devices to evaluate how chemical dispersants change asphaltene deposition. Four commercially used alkyl-phenol model chemical dispersants are tested with model oils flowing through porous media, and the resulting deposition kinetics are visualized at both the matrix-scale and the pore-scale. Interestingly, initial asphaltene deposition worsens in the presence of the tested dispersants, but the mechanism by which plugging and permeability reduction in the porous media varies. The velocity profiles near the deposit are analyzed to further investigate how shear forces affect asphaltene deposition. The deposition tendency is also related to the intermolecular interactions governing the asphaltene-dispersant systems. Furthermore, the model system is extended to a real case. The use of porous media microfluidic devices offers a unique
The ability to precisely control the motion of droplets is essential in droplet-based microfluidics. It serves as the basis for various droplet-based devices. This paper presents a thermal control technique for microdroplets at a bifurcation. Control was achieved using an integrated microheater that simultaneously induces a reduction in fluidic resistance and thermocapillarity. The temperature of the heater was monitored by an integrated temperature sensor. At a bifurcation with symmetric branches, a droplet can be split into two daughter droplets of controllable sizes or entirely switched into a desired branch. The physics of this phenomenon was investigated with the help of a numerical model. Splitting and switching were demonstrated within an operational temperature range of 25 to 38 • C. The relatively low operational temperature range allows this technique to be used for droplets containing biological samples. The present control concept is not limited to bifurcations, but can be employed in other geometries.
The authors used thermally induced surface tension gradients to manipulate aqueous droplets in microchannels. Control of the droplet breakup process was demonstrated. Droplet sorting can be achieved with temperatures above a critical value. Numerical simulation using a two-dimensional model agrees qualitatively well with the experimental results. The used control temperature of less than 55°C shows that this active control concept is suitable for biochemical applications. Thermal control promises to be a simple and effective manipulation method for droplet-based lab on a chip
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