BaTiO3 and PZT films were prepared by single-step dip-coating from alkoxide-acetate solutions containing polyvinylpyrrolidone (PVP). Crack-free BaTiO3 and PZT films over 1 μm in thickness were obtained via single-step deposition. Stepwise heating of the gel films was found to improve densification of BaTiO3 films, reducing the thickness and increasing the optical transmittance, which was not, however, the case with PZT films, where the stepwise heating rather induced crack formation, leading to degraded transmittance. Residual stress was evaluated on spin-coating BaTiO3 films by measuring the substrate curvature, where a significant reduction in tensile stress was found to be caused by PVP.
A high c-axis-oriented and atomically flat-surface aluminum nitride (AlN) film has been successfully deposited on a (0001)sapphire substrate by metalorganic chemical vapor deposition. We evaluated the dependences of surface roughness, tilted mosaicity and twisted mosaicity on the conditions of AlN deposition. It was found that the atomically flat-surface AlN film was deposited under the diffusion-limited area with suppression of vapor phase reaction at a substrate temperature of 1200 C and a V/III ratio of 800. It was also recognized that surface roughness was controlled by gas flow velocity, which is determined by both gas flow rate and pressure in reactor. Mean surface roughness (R a ) of the deposited AlN films was approximately 1A. The full width at half maximum of X-ray rocking curve for (0002) and ð10 1 12ÞAlN were approximately 100 and 2300 arcsec, respectively.
This paper describes a millimeter-wave broadband monolithic even harmonic image rejection mixer with a ring connected anti-parallel diode pair. This mixer employs an even harmonic mixer with a ring connected anti-parallel diode pair to reduce the LO leakage. Also it employs the balanced type mixer with the Marchand balun to broaden the frequency range. Furthermore, the configuration of the image rejection mixer can suppress the image components.The chip size of the developed millimeterwave broadband monolithic mixer is 1.2 mm x 2.9 mm on a GaAs substrate. Conversion loss is less than 15.9 dB and image rejection ratio is more than 12.5 dB from 24 to 44 GHz. Broadband characteristics can be achieved by the proposed configuration.
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