Antiaromatic moieties fused in polycyclic π-conjugated molecules usually exhibit strong localized antiaromaticiy. Herein, we reported the synthesis and properties of a bisazapentalene dication (BAP 2+ ) obtained from in situ two-electron oxidation of neutral species 8. Noteworthily, it possesses global aromaticity and an open-shell singlet ground state. This study underlines the importance of heteroatoms in determining the delocalization of π-electrons and the aromaticity of molecules in their oxidized states.

Estimation of the aerodynamic load on trees is essential for urban tree management to mitigate the risk of tree failure. To assess that in a cost-effective way, scaled down tree models and numerical simulations were utilized. Scaled down tree models reduce the cost of experimental studies and allow the studies to be conducted in a controlled environment, namely in a wind or water tunnel, but the major challenge is to construct a tree model that resembles the real tree. We constructed 3D-printed scaled down fractal tree models of major urban tree species in Singapore using procedural modelling, based on species-specific growth processes and field statistical data gathered through laser scanning of real trees. The tree crowns were modelled to match the optical porosity of real trees. We developed a methodology to model the tree crowns using porous volumes filled with randomized tetrahedral elements. The wind loads acting on the tree models were then measured in the wind tunnel and the velocity profiles from selected models were captured using particle image velocimetry (PIV). The data was then used for the validation of Large Eddy Simulations (LES), in which the trees were modelled via a discretized momentum sink with 10–20 elements in width, height, and depth, respectively. It is observed that the velocity profiles and drag of the simulations and the wind tunnel tests are in reasonable agreement. We hence established a clear relationship between the measured bulk drag on the tree models in the wind tunnel, and the local drag coefficients of the discretized elements in the simulations. Analysis on the bulk drag coefficient also shows that the effect of complex crown shape could be more dominant compared to the frontal optical porosity.

In this work, we adopt the integration of the L-system fractal tree generation, 3D printed wind tunnel modeling, and computational fluid dynamics (CFD) simulation approach to model the wind effect on a single tree. We compare the agreement between CFD simulations and wind tunnel measurements of rigid branched structures resembling trees. First, fractal tree mesh models based on species growth and branching patterns are developed to represent tree species for wind–tree modeling. Subsequently, a scaled-down fractal tree is generated with 3D-printing and subjected to tunnel testing with load cell and particle image velocimetry measurement data under the wind speed of 10 m/s and 15 m/s. Finally, CFD based on Reynolds-Average Navier–Stokes (RANS) simulation with a full closure model and Large Eddy Simulation (LES) using appropriate momentum sink and turbulence source terms for the volumetric tree is carried out. We use both the volume-average porous media and the volume-splitting discretized zones (split number 10 × 10 × 10) to reproduce the momentum sink effect in the numerical simulation. Three tree species, namely, Peltophorum pterocarpum (yellow flame), Khaya senegalensis (African mahogany), and Hopea odorata (ironwood), are tested, and a reasonable agreement of drag force prediction and velocity profiles is obtained when comparing the CFD simulation results with wind tunnel data. The RANS modeled drag force results exhibit 20% of over-prediction, while the normalized velocity profiles display a good match of velocity decay at the tree leeward sides. On the other hand, LES produces much better results with only 3% discrepancy with the experimental results. A comparison of experimental results among the tree species is also carried out. Due to the actual random wind direction, tree slenderness representation, and structural flexibility issues, the current methodology still has the limitation for validation with urban on-site measurement. Nonetheless, this integrated approach is the first step in establishing modeling tool applicability to examine the effect of the forest structure and composition on wind loads.

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