The s-process should occur in all but the lower mass progenitor stars of planetary nebulae, and this should be reflected in the chemical composition of the gas that is expelled to create the current planetary nebula shell. Weak forbidden emission lines are expected from several s-process elements in these shells and have been searched for and in some cases detected in previous investigations. Here we extend these studies by combining very high signal-to-noise ratio echelle spectra of a sample of PNe with a critical analysis of the identification of the emission lines of Z > 30 ions. Emission lines of Br, Kr, Xe, Rb, Ba, and Pb are detected with a reasonable degree of certainty in at least some of the objects studied here, and we also tentatively identify lines from Te and I, each in one object. The strengths of these lines indicate enhancement of s-process elements in the central star progenitors, and we determine the abundances of Br, Kr, and Xe, elements for which atomic data relevant for abundance determination have recently become available. As representative elements of the ''light'' and ''heavy''s-process peaks, Kr and Xe exhibit similar enhancements over solar values, suggesting that PN progenitors experience substantial neutron exposure.

Unidentified infrared emission bands at wavelengths of 3-20 micrometres are widely observed in a range of environments in our Galaxy and in others. Some features have been identified as the stretching and bending modes of aromatic compounds, and are commonly attributed to polycyclic aromatic hydrocarbon molecules. The central argument supporting this attribution is that single-photon excitation of the molecule can account for the unidentified infrared emission features observed in 'cirrus' clouds in the diffuse interstellar medium. Of the more than 160 molecules identified in the circumstellar and interstellar environments, however, not one is a polycyclic aromatic hydrocarbon molecule. The detections of discrete and broad aliphatic spectral features suggest that the carrier of the unidentified infrared emission features cannot be a pure aromatic compound. Here we report an analysis of archival spectroscopic observations and demonstrate that the data are most consistent with the carriers being amorphous organic solids with a mixed aromatic-aliphatic structure. This structure is similar to that of the organic materials found in meteorites, as would be expected if the Solar System had inherited these organic materials from interstellar sources.

We present high-quality optical spectroscopic observations of the planetary nebula (PN) Hf 2-2. The spectrum exhibits many prominent optical recombination lines (ORLs) from heavy-element ions. Analysis of the H I and He I recombination spectrum yields an electron temperature of ∼900 K, a factor of 10 lower than given by the collisionally excited [O III] forbidden lines. The ionic abundances of heavy elements relative to hydrogen derived from ORLs are about a factor of 70 higher than those deduced from collisionally excited lines (CELs) from the same ions, the largest abundance discrepancy factor (adf) ever measured for a PN. By comparing the observed O II λ4089/λ4649 ORL ratio to theoretical value as a function of electron temperature, we show that the O II ORLs arise from ionized regions with an electron temperature of only ∼630 K. The current observations thus provide the strongest evidence that the nebula contains another previously unknown component of cold, high-metallicity gas, which is too cool to excite any significant optical or ultraviolet CELs and is thus invisible via such lines. The existence of such a plasma component in PNe provides a natural solution to the long-standing dichotomy between nebular plasma diagnostics and abundance determinations using CELs on the one hand and ORLs on the other.