No abstract

The adsorption capacities of carbon dioxide on six commercial hydrotalcite-like compounds and the main factors (aluminum content, anion type, water content, and heat treatment temperature) influencing their adsorption capacity at high temperatures have been investigated using a gravimetric technique. There is an optimum aluminum content and heat treatment temperature for the adsorption capacity. The carbonate anion favors adsorption of carbon dioxide compared to OH-, and a low content of water also improves the adsorption capacity. The carbon dioxide adsorption capacity is mainly dependent on the microporous volume, interlayer spacing, and layer charge density of the hydrotalcite-like compounds.

A simple and effective method denoted "pH-adjusting" is used to graft a large amount of heteroatoms such as Al and Ti to mesoporous silica material SBA-15. The products prepared by this method show highly ordered mesostructures with large surface areas and uniform mesopore size distribution. The results of ICP, EDX, 27 Al NMR, calcium ion-exchange capacity, and UV-vis spectra show that almost all the heteroatoms added into the initial reaction mixture can be introduced into the products, and moreover, the heteroatoms introduced by this route locate at mainly tetrahedrally coordinated sites. CM0343857 492

No abstract

Effective activation of CO2 is a prerequisite for efficient utilization of CO2 in organic synthesis. Precisely controlling the interfacial events of solids shows potential for activation. Herein, defect-enriched CeO2 with constructed interfacial frustrated Lewis pairs (FLPs, two adjacent Ce3+···O2–) effectively activates CO2 via the interactions between C/Lewis basic lattice O2– and the two O atoms in CO2/two adjacent Lewis acidic Ce3+ ions. Selective cyclic carbonate production from a catalytically tandem protocol of olefins and CO2 is used to demonstrate FLP-inspired CO2 activation.