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An experimental technique is developed to measure the interfacial tensions of the crude oil + reservoir brine + CO 2 systems at pressures from (0.1 to 31.4) MPa and two temperatures (27 and 58) °C using the axisymmetric drop shape analysis (ADSA) technique for the pendant drop case. The measured dynamic interfacial tension is gradually reduced to an equilibrium value. For both the reservoir brine + CO 2 system and the crude oil + CO 2 system, the equilibrium interfacial tension decreases as the pressure increases, whereas it increases as the temperature increases. For the reservoir brine + CO 2 system, the interfacial tension data are not available at P g 12.238 MPa and 58 °C because the pendant brine drop cannot be formed in the CO 2 phase. However, for the crude oil + CO 2 system, the equilibrium interfacial tension remains almost constant at P g 8.879 MPa and 27 °C or at P g 13.362 MPa and 58 °C. Under the same conditions, nevertheless, the equilibrium interfacial tension of the crude oil + reservoir brine + CO 2 system is reduced in comparison with that of the crude oil + reservoir brine system. The interfacial tension reduction for the crude oil + reservoir brine + CO 2 system is larger at higher pressures.

In this paper, the mass transfer of CO 2 into a reservoir brine sample is studied experimentally at high pressures and elevated temperatures. The equilibrium concentration of CO 2 in the reservoir brine and the density of CO 2 -saturated brine are measured by saturating the brine with CO 2 . The mass-transfer rate of CO 2 into the brine is determined by monitoring the pressure decay inside a closed, visual, high-pressure PVT cell. It is found that the density of the brine with dissolved CO 2 increases linearly with CO 2 concentration. As CO 2 gradually dissolves into the brine by molecular diffusion, a concentration-induced density gradient is generated near the CO 2 -brine interface. Under the influence of gravity, this concentration-induced density gradient causes natural convection, which accelerates the mass-transfer rate of CO 2 into the brine. The modified diffusion equation with an effective diffusivity is applied to model the mass-transfer process. It is found that the determined effective diffusivities of CO 2 in the reservoir brine are almost two orders of magnitude larger than the molecular diffusivities of CO 2 in water or similar reservoir brines. The detailed experimental results show that the density-driven natural convection greatly accelerates the dissolution process of CO 2 in brine. This means that loss of CO 2 in brine can be significant in an enhanced oil recovery operation using CO 2 flooding in an oil reservoir with a bottom water aquifer. More importantly, the accelerated mass transfer due to the density-driven natural convection significantly increases the geological sequestration rate of CO 2 in deep saline formations.