A high-resolution carbon-isotope curve derived from Upper Cretaceous hemipelagic sediments cropping out at Tingri, southern Tibet, shows similarities to patterns established on other continents, notably in the presence of a well-defined positive excursion across the Cenomanian–Turonian boundary where δ 13 C values exceed 3.5‰. From the upper Turonian to the lower Campanian, δ 13 C values generally decline, apart from a minor positive excursion in the middle Coniacian: a trend that departs from that recorded from Europe. Relatively low δ 13 C values ( c . 1‰) at the Santonian–Campanian and Campanian–Maastrichtian boundaries in Tibet define a prominent broad positive excursion centred in the middle Campanian and terminated by an abrupt fall towards the close of the stage. When compared with data from Europe and North Africa, the δ 13 C values of the Tibetan section are generally lower by c . 1.5‰, except for the middle Campanian positive excursion where values (δ 13 C c . 2‰) are comparable with those documented from Europe and North Africa. These differences are interpreted as reflecting variable mixing of water masses carrying different carbon-isotope signatures, such that areas close to the major sinks of marine organic carbon recorded higher δ 13 C values than those located in more distal regions. Oxygen-isotope ratios, albeit affected by diagenesis, may record a palaeotemperature signal.

No abstract

No abstract

High spatial resolution carbon dioxide (CO2) flux inversion systems are needed to support the global stocktake required by the Paris Agreement and to complement the bottom-up emission inventories. Based on the work of Zhang, a regional CO2 flux inversion system capable of assimilating the column-averaged dry air mole fractions of CO2 (XCO2) retrieved from Orbiting Carbon Observatory-2 (OCO-2) observations had been developed. To evaluate the system, under the constraints of the initial state and boundary conditions extracted from the CarbonTracker 2017 product (CT2017), the annual CO2 flux over the contiguous United States in 2016 was inverted (1.08 Pg C yr−1) and compared with the corresponding posterior CO2 fluxes extracted from OCO-2 model intercomparison project (OCO-2 MIP) (mean: 0.76 Pg C yr−1, standard deviation: 0.29 Pg C yr−1, 9 models in total) and CT2017 (1.19 Pg C yr−1). The uncertainty of the inverted CO2 flux was reduced by 14.71% compared to the prior flux. The annual mean XCO2 estimated by the inversion system was 403.67 ppm, which was 0.11 ppm smaller than the result (403.78 ppm) simulated by a parallel experiment without assimilating the OCO-2 retrievals and closer to the result of CT2017 (403.29 ppm). Independent CO2 flux and concentration measurements from towers, aircraft, and Total Carbon Column Observing Network (TCCON) were used to evaluate the results. Mean bias error (MBE) between the inverted CO2 flux and flux measurements was 0.73 g C m−2 d−1, was reduced by 22.34% and 28.43% compared to those of the prior flux and CT2017, respectively. MBEs between the CO2 concentrations estimated by the inversion system and concentration measurements from TCCON, towers, and aircraft were reduced by 52.78%, 96.45%, and 75%, respectively, compared to those of the parallel experiment. The experiment proved that CO2 emission hotspots indicated by the inverted annual CO2 flux with a relatively high spatial resolution of 50 km consisted well with the locations of most major metropolitan/urban areas in the contiguous United States, which demonstrated the potential of combing satellite observations with high spatial resolution CO2 flux inversion system in supporting the global stocktake.