Over the past decade or so, there has been increasing interest in the synthesis of polymer particles with surface concavities, which mainly include golf ball‐like, dimpled and surface‐wrinkled polymer particles. Such syntheses generally can be classified into direct polymerization and post‐treatment on preformed polymer particles. This review aims to provide an overview of the synthetic strategies of such particles. Some selected examples are given to present the formation mechanisms of the surface concavities. The applications and future development of these concave polymer particles are also briefly discussed.

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