The lateral size effect of graphene oxide (GO) on surfaced-enhanced Raman scattering (SERS) property is systematically investigated by using size-fractionalized GO. For the size fractionalization without changes of chemical structure, large-sized GO (LGO) and small-sized GO (SGO) are separated from the assynthesized GO (AGO) by centrifugation and membrane filtration, respectively. The size-fractionalized GO sheets are immobilized on a solid substrate for the parallel comparison of their SERS property. As a result, we find that LGO shows considerably higher SERS property than SGO for typical Raman probes such as rhodamine 6G and crystal violet. Furthermore, the lateral size effect of GO derivatives is consistently observed when they are hybridized with plasmonic silver nanoparticles. These results indicate that LGO is superior to AGO and SGO as a SERS platform, and it is also quantitatively confirmed by calculating their enhancement factor.

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An efficient protection strategy for silver nanowirebased transparent electrodes (AgNW TEs) is developed to enhance their poor adhesion force on substrates and thermal, optical, chemical, and electrical stabilities. Chitin nanofibers (CNFs) and alkali lignin (AL), which possess high mechanical property, a gas/ moisture barrier, and UV absorption properties, are successively assembled on AgNW TEs through layer-by-layer (LBL) assembly based on their oppositely charged surfaces. The formation of LBLassembled CNFs and AL (CNF/AL) 10 bilayers, where 10 is the optimized number of bilayers, on the aldehyde-modified AgNW (Al-AgNW) TEs does not deteriorate their electrical conductivity (17.3 ± 2.1 Ω/□) and transmittance (90.