The low modulus β type titanium alloy, Ti-29Nb-13Ta-4.6Zr, was designed, and then the practical level ingot of the alloy was successfully fabricated by Levicast method. The mechanical and biological compatibilities, and super elastic behavior of the alloys were investigated in this study. The mechanical performance of tensile properties and fatigue strength of the alloy are equal to or greater than those of conventional biomedical Ti-6Al-4V ELI. Young's modulus of the alloy is much lower than that of Ti-6Al-4V ELI, and increases with the precipitation of α phase or ω phase in the β matrix phase. The compatibility of the alloy with bone is excellent. Low modulus of the alloy is effective to enhance the healing of bone fracture and remodeling of bone. Super elastic behavior is observed in Ti-29Nb-13Ta-4.6Zr conducted with short time solution treatment after heavy cold working. Total elastic strain in that case is around 2.8 %. The mechanism of the super elastic behavior of Ti-29Nb-13Ta-4.6Zr is still unclear.
Ti–Ni–Pd shape memory alloys are promising candidates for high-temperature actuators operating at above 373 K. One of the key issues in developing high-temperature shape memory alloys is the degradation of shape memory properties and dimensional stabilities because plastic deformation becomes more pronounced at higher working temperature ranges. In this study, the effect of the Ti:(Ni + Pd) atomic ratio in TixNi70−xPd30 alloys with Ti content in the range from 49 at.% to 52 at.% on the martensitic transformation temperatures, microstructures and shape memory properties during thermal cycling under constant stresses were investigated. The martensitic transformation temperatures decreased with increasing or decreasing Ti content from the stoichiometric composition. In both Ti-rich and Ti-lean alloys, the transformation temperatures decreased during thermal cycling and the degree of decrease in the transformation temperatures became more pronounced as the composition of the alloy departed from the stoichiometric composition. Ti2Pd and P phases were formed during thermal cycling in Ti-rich and Ti-lean alloys, respectively. Both Ti-rich and Ti-lean alloys exhibited superior dimensional stabilities and excellent shape memory properties with higher recovery ratio and larger work output during thermal cycling under constant stresses when compared with the alloys with near-stoichiometric composition.
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