Co3V2O8 thin nanoplates are firstly described as a kind of electrode material for supercapacitors. More importantly, from electrochemical measurements, the obtained Co3V2O8 nanoplate electrode shows a good specific capacitance (0.5 A g−1, 739 F g−1) and cycling stability (704 F g−1 retained after 2000 cycles). This study essentially offers a new kind of metal vanadium oxides as electrochemical active material for the development of supercapacitors.
Mesoporous 3D architectures of silicon dioxide, nickel silicate, and cobalt silicate are for the first time prepared by using reed leafs as a sustainable silica source. Due to the 3D mesoporous architecture, nickel and cobalt silicate allow efficient charge transfer and mass transport, while at the same time buffering the volume changes during ion lithiation/delithiation processes. Especially, the nickel silicate electrode with the mesoporous 3D architecture shows a high specific capacitance, a good rate capability, and cycling stability for electrochemical capacitors.
This work describes the first demonstration of nanocrystal plane dependent nonenzymatic electro-catalytic glucose activity of [Cu3(btc)2] nanocrystals with different shapes (nanocube, truncated cube, cuboctahedron, and octahedron). From electrochemical results, the obtained [Cu3(btc)2] nanocube modified electrode shows the best nonenzymatic electro-catalytic glucose activity. Interestingly, decreasing the {100} crystal planes from cubes to octahedra, changes the nonenzymatic electro-catalytic activity from highly sensitive to general.
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