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ABSTRACT:A new method of preparation of living cationic polymer of isobutyl vinyl ether via photoinduced polymerization in the presence of diphenyliodonium iodide (DPII, initiator) and zinc iodide in a mixed solvent of toluene/diethyl ether, which was irradiated at Ϫ78°C for short period, was completed within 15 min. The reaction was allowed for further reaction in the dark until monomer was fully consumed. It was found that increase in the conversion of monomer to polymer during the irradiation is very limited. Confirmation of the linear dependence of numberaverage molar mass of resulting polymer on % conversion together with the fact that polymerization proceeds until monomer consumption, and controllability of number-average molar mass of resulting polymer, depending on the molar ratio of monomer and initiator, strongly suggests the living nature of this polymerization, unless reaction temperature becomes higher than 0°C, i.e., the absence of chain breaking process. The narrow molar mass distribution, whose polydispersity index values are less than 1.2, reveals that the rate of initiation where irradiation is usually completed within 15 min is much faster than that of propagation in cationic nature in this system. Effect of some major factors, such as solvent polarity and temperature, on the living nature of the polymerization was also investigated.

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Depth sensing is an important issue in many applications, such as Augmented Reality (AR), eXtended Reality (XR), and Metaverse. For 3D reconstruction, a depth map can be acquired by a stereo camera and a Time-of-Flight (ToF) sensor. We used both sensors complementarily to improve the accuracy of 3D information of the data. First, we applied a generalized multi-camera calibration method that uses both color and depth information. Next, depth maps of two sensors were fused by 3D registration and reprojection approach. Then, hole-filling was applied to refine the new depth map from the ToF-stereo fused data. Finally, the surface reconstruction technique was used to generate mesh data from the ToF-stereo fused pointcloud data. The proposed procedure was implemented and tested with real-world data and compared with various algorithms to validate its efficiency.

Universal Plug and Play (UPnP) can be applied many home appliances because of its straightforward implementation and zero configuration characteristics. However, it has limitation of the cost and spatial because it has to be used in IP based network. The proposed network bridge is capable of generating virtual Zigbee device without implementing each actual device which inserts an UPnP stack. This technique is promising for seamless inter-networking with Zigbee and UPnP network. Also, the architecture of the proposed network bridgecan be applied implementation for a future smart home.