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Metal-containing Fenton catalysts have been widely investigated. Here, we report for the first time a highly effective stable metal-free Fenton-like catalyst with dual reaction centers consisting of 4-phenoxyphenol-functionalized reduced graphene oxide nanosheets (POP-rGO NSs) prepared through surface complexation and copolymerization. Experimental and theoretical studies verified that dual reaction centers are formed on the C-O-C bridge of POP-rGO NSs. The electron-rich center around O is responsible for the efficient reduction of HO to OH, while the electron-poor center around C captures electrons from the adsorbed pollutants and diverts them to the electron-rich area via the C-O-C bridge. By these processes, pollutants are degraded and mineralized quickly in a wide pH range, and a higher HO utilization efficiency is achieved. Our findings address the problems of the classical Fenton reaction and are useful for the development of efficient Fenton-like catalysts using organic polymers for different fields.

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A new class of superhydrophobic surface based on multiple hybrid coatings is proposed and prepared to improve mechanical and reproduction stability. It does not only show a large water contact angle (ca. 174.5°) but also a slight decrease (ca. 6.4%) of water contact angle after 100 mechanical abrasion cycles. Furthermore, the water contact angle changes slightly (relative standard deviation, 0.14%) for the three superhydrophobic surfaces prepared with the same procedure. The application of superhydrophobic multiple hybrid coatings in corrosion protection is further investigated by the Tafel polarization curves and electrochemical impedance spectroscopy. The superhydrophobic multiple hybrid coatings showed lower corrosion current (1.4 × 10–11 A/cm2), lower corrosion rate (ca. 1.6 × 10–7 mm/year), and larger polarization resistance (7.9 × 104 MΩ cm2) in 3.5 wt % NaCl aqueous solution compared to other superhydrophobic coatings reported in previous works. This work not only confirms the formation of robust superhydrophobic surface for real application in corrosion protection but also provides a new model of superhydrophobic surface based on multiple hybrid coatings with high mechanical, chemical, and reproduction stability for various applications.