High‐nitrogen stainless steel (HNSS) is prone to surface depression during continuous casting; however, its high‐temperature solidification characteristics and mold powder design have not been reported. Based on the analysis of mold thermocouple temperature variation, this study clarifies the high‐temperature solidification characteristics of HNSS and the cause of surface depression. It optimizes the mold powder for HNSS continuous casting according to factory and laboratory research. The factory trials indicate that the mold thermocouple temperature at the corresponding location decreases by 6.0–20.9 °C when the slab surface is depressed. The analysis shows that the high initial solidification strength of HNSS causes its slab surface depressions. Owing to this characteristic, the mold powder for HNSS should have a suitable melting rate, low basicity, and proper Al2O3. This low‐basicity Al2O3‐containing slag has a crystal slag film near the mold side and a thick liquid slag film near the slab. It can both provide good lubrication and control horizontal heat transfer.

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Carbon materials play an important role in controlling the sintering and melting behaviors of mold flux. However, the reactions between carbon and mold fluxes and corresponding effects on the properties of mold fluxes are ignored in previous studies. The effects of carbon black on the sintering and melting behavior of mold flux during the heating process were systematically investigated by TG-FTIR, DSC, XRD, TEM, SEM, XPS, Raman spectroscopy, and viscosity measurement. The results showed that: carbon black between the mineral particles was visualized by TEM, and Ca 4 Si 2 O 7 F 2 as sintering phase was not formed until 1 300°C in CaO-SiO 2 -CaF 2 -Na 2 O slag on account of the insulation of carbon black. Residual carbon black absorbed on the surface of slag droplets suppressed the melting by preventing the aggregation of droplets. Besides, SiC as production of the carbon-slag reaction significantly increased the slag viscosity by improving the polymerization degree of molten slag.