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The novel packaging was synthesised by coating polyvinyl chloride (PVC) film with Polyvinylamine/Polyvinyl alcohol (PVAm/PVA) mixture which can effectively inhibit the migration of DOP in this paper. The effect of PVAm/PVA mixture on inhibiting DOP migration was detected via extraction tests. The results showed that the novel packaging significantly reduced the migration rate of DOP compared with the control (PVC film). After 24h extracted by hexane 40% PVAm in mixture being coated on PVC had the lowest migration rate (6.20%) among the samples, while 7.60% is the migration rate of control sample. Tensile properties analysis indicated the elongation at break and tensile strength of samples coating PVAm/PVA higher than control sample. The thermogravimetric analysis demonstrated that the PVAm/PVA mixed solution can deduce thermogravimetric rate. Therefore, coating PVC with PVAm/PVA mixture is an effective approach to suppress the migration of DOP.