Defects in thin film silicon with different structure all the way from amorphous to microcrystalline were investigated by electron spin resonance with emphasis on amorphous material prepared close to the transition to crystalline growth. Electron beam irradiation and stepwise annealing is used for reversible variation of the defect density over three orders of magnitude. The electron irradiation enhances mainly the native paramagnetic defects. Additional resonances are found as satellites to the central line, which anneal rapidly at temperatures below 100 °C. These features are most pronounced for the amorphous material prepared close to the transition to crystalline growth. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
We report on drastic change of vortex dynamics with increase of quenched disorder: for rather weak disorder we found a single vortex creep regime, which we attribute to a Bragg-glass phase, while for enhanced disorder we found an increase of both the depinning current and activation energy with magnetic field, which we attribute to entangled vortex phase. We also found that introduction of additional defects always increases the depinning current, but it increases activation energy only for elastic vortex creep, while it decreases activation energy for plastic vortex creep.PACS numbers: 74.60. Jg, 74.60.Ge, 74.60.Ec, 74.72.Bk The effect of random pinning on crystalline order and on dynamics of the flux-line-lattice (FLL) was a subject of numerous experimental and theoretical investigations. . The field H on was interpreted as a phase boundary between low field ordered and high field disordered vortex phases. These experimental results are supported by theoretical studies. It was shown that in presence of rather weak disorder the FLL retains a quasilong-range order resulting in the so-called Bragg glass phase [4]. However, with the increase of random pinning or magnetic field a transition to strongly disordered entangled vortex phase (glass phase) is predicted [5,6]. A sharp increase in magnetization below the fish-tail peak position H p was observed in N d 1.85 Ce 0.15 CuO 4−d [7] and non twinned YBa 2 Cu 3 O 7−δ [8] single crystals.Magnetic measurements showed that in optimally doped YBa 2 Cu 3 O 7−δ crystals no fishtail behavior is observed both in detwinned [9] and twinned [10] samples, while decrease of the oxygen content always induced non monotonous J m (H)-curves. Two distinctive peculiarities in the magnetization curves of oxygen deficient [10] and electron irradiated [11] crystals were observed: (1) the peaks H on and H p shift toward lower magnetic fields with increasing defect concentration, and (2) in magnetic fields H < H p the current J m increases, while in magnetic fields H > H p the current J m decreases with increasing defect concentration. It is believed [12,13] that the peak H p separates elastic vortex creep in low and plastic vortex creep, mediated by motion of the FLL dislocations, in high magnetic fields. Thus the introduction of additional defects leads to an increase of vortex pinning in the region of elastic creep and such behavior is expected. On the other hand, decrease of pinning force with increasing disorder observed in the region of plastic creep is non trivial, and reasons of such behavior are not known. The aim of this paper is to show the effect of point-like defects concentration on vortex dynamics and pinning parameters in YBa 2 Cu 3 O 7−δ single crystals.The investigated sample was YBa 2 Cu 3 O 7−δ single crystal with T c ≈ 93.5 K and ∆T c < 0.5 K. Twin planes (TP's) inside the measured part of the sample were aligned in one direction. The transport current was applied along the ab-plane and at an angle α = 45 • with respect to TP's. Measurements were performed in magnet...
After irradiation of hydrogenated amorphous and microcrystalline silicon (a-Si:H and μc-Si:H) with 2 MeV electrons at 100 K, we observe satellite-like components close to the dominating electron spin resonance (ESR) signal of these materials. The satellites overlap with the commonly observed dangling bond resonance and are proposed to originate from a hyperfine interaction with the nuclear magnetic moment of hydrogen atoms in a-Si:H and μc-Si:H. Our present study is focused on the verification of this hypothesis. Equivalent hydrogenated and deuterated a-/μc-Si:H/D materials have been investigated with ESR before and after 2 MeV electron bombardment. From the difference between ESR spectra of hydrogenated and deuterated samples we identify the doublet structure in the ESR spectra as a hyperfine pattern of hydrogen-related paramagnetic centers. The observations of H-related paramagnetic centers in a-/μc-Si:H are of particular interest in view of metastability models of a-Si:H, which include H-related complexes as precursors for the stabilization of the metastable Si dangling bonds. The nature of the observed center is discussed in the light of known H-related complexes in crystalline Si and suggested H-related dangling bonds in a-Si:H.
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