Fiber-based sensors are desirable to provide an immersive experience for users in the human−computer interface. We report a hierarchically porous silver nanowire-bacterial cellulose fiber that can be utilized for sensitive detection of both pressure and proximity of human fingers. The conductive fiber was synthesized via continuous wetspinning at a speed of 20 m/min, with a diameter of 53 μm, the electrical conductivity of 1.3 × 10 4 S/cm, a tensile strength of 198 MPa, and elongation strain of 3.0% at break. The fibers were coaxially coated with a 10 μm thick poly(dimethylsiloxane) dielectric elastomer to form the fiber sensor element which is thinner than a human hair. Two of the sensor fibers were laid diagonally, and the capacitance changes between the conductive cores were measured in response to pressure and proximity. In the touch mode, a fiber-based sensor experienced monotonic capacitance increase in the pressure range from 0 to 460 kPa, and a linear response with a high sensitivity of 5.49 kPa −1 was obtained in the low-pressure regime (<0.5 kPa). In touchless mode, the sensor is highly sensitive to objects at a distance of up to 30 cm. Also, the fiber can be easily stitched into garments as comfortable and fashionable sensors to detect heartbeat and vocal pulses. A fiber sensor array is able to serve as a touchless piano to play music and accurately determine the proximity of an object. A 2 × 2 array was further shown for two-and threedimensional location detection of remote objects.
Single- or few-layered h-BN nanosheets (BNNSs) are analogous to graphene and possess unique properties. However, their technological applications were severely hindered by the low production efficiency of BNNSs. We reported here a study in which BNNSs were efficiently produced by exfoliating bulk h-BN powder in thionyl chloride without using any dispersion agents. The BNNSs yield was as high as 20%, and it could be doubled through the second round of exfoliation of the h-BN precipitate. Microscopic results revealed that the BNNSs generally consisted of 3-20 layers. Pd nanoparticles were successfully immobilized and uniformly distributed on BNNS surfaces through the deposition-precipitation method. The resultant Pd-BNNS catalyst exhibited high catalytic activity and recyclability for the hydrogenation of nitro aromatics, demonstrating that BNNSs served as a promising platform to fabricate heterogeneous catalysts.
We demonstrate a single-phase, two-way
shape actuator that, in
the absence of an external load, elongates upon cooling and reversibly
contracts upon heating. In a simple and straightforward process, a
partially cross-linked, semicrystalline poly(ε-caprolactone)
(PCL) network is melted, stretched to several hundred percent strain,
and further cross-linked. Upon removal of the applied load, the elastic
double network adopts a “state-of-ease” that retains
part of its former strain. When cooled, internal stress-induced crystallization
causes further elongation of configurationally biased chains. When
heated, crystallites melt, and the sample returns to its equilibrium
state-of-ease. Under optimized conditions, reversible actuation >15%
strain can be reproducibly achieved, and samples can be cycled multiple
times with highly uniform actuation with no observable creep. The
mechanism behind such actuation was further confirmed via calorimetry
and X-ray scattering.
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