No abstract

The quantitative evaluation of azelaic acid is becoming critical in the development of new medicinal products and in environment. A feasible method for the determination of azelaic acid in cosmetics by gas chromatographic-mass spectrometer detector (GC-MS) with derivation was developed and optimized. The derivative effect was good, when azelaic acid was derivatized through ethanol at room temperature for 10 min with 800 μL of sulfuric acid as a catalyst. A good linear relationship of azelaic acid derivative was present from 10 to 1000 mg L –1 ( R 2 = 0.9997). Detection limit and quantitative limit of GC was 15 and 50 mg kg –1 , respectively. The recovery rate was in the range from 87.7% to 101% with all relative standard deviation (RSD) values less than 4%, denoting the method meeting the requirement of the analysis. Therefore, this method has the advantages of strong anti-interference ability and accurate results. Among the eight samples nominally azelaic acid, only three were detected. The respective content was 78 133, 16 710, and 2431 mg kg –1 . The results showed that the actual addition of the azelaic acid in the market was quite different with label identification, being worthy of further attention. Further, it also provided a favorable experience for the monitoring of azelaic acid in the environment.

A hybrid system of flocculation−photocatalysis (HSFP) was applied to evaluate the color removal from simulative dye wastewater. The decolorization performance of HSFP was investigated considering four key factors: flocculant dosage, pH, turbidity, and ionic strength. Compared with flocculation alone, HSFP showed better decolorization effectiveness for simulative Crystal Violet−Reactive Red X-3B dye wastewater (CV-RR) and simulative Crystal Violet−Acid Orange II dye wastewater (CV-AO). The dosage of flocculant was determined by the molecular structure of target dyes. A higher dosage was required for the color removal of dyes with a lower molecular weight and less sulfonic acid groups. The dominant decolorization mechanism was different with different initial pH values of simulative dye wastewater, which influenced the decolorization efficiency of flocculation and photocatalysis. For dyes with a lower molecular weight and less sulfonic acid groups, better decolorization performance was achieved under neutral conditions, mainly depending on strong charge neutralization and adsorption bridging capacity. For dyes with a higher molecular weight and more sulfonic acid groups, decolorization efficiency was improved with an increase in pH, due to stronger deprotonation. An increase of turbidity reduced the dye removal efficiency of flocculation alone and HSFP. The presence of NaCl, CuCl 2 , and CrCl 3 led to a different decrease in the flocculation efficiency and photodegradation efficiency.