Instead of carbon, Mo2C is used to modify the MoO2 material for the first time. The presence of highly conductive and electrochemical inactive Mo2C decreases the resistance of the charge transport and enhances the structural stability of MoO2 nanoparticles upon lithiation and delithiation, ensuring the superior cycling stability and high rate capability of the heteronanotubes. Cycled at 200 and 1000 mA g−1 for 140 cycles, the discharge capacities of the MoO2/Mo2C heteronanotubes remain to be 790 and 510 mAh g−1, respectively. This work demonstrates the potential of the novel heteronanotubes for application as an electrode material for high‐performance Li‐ion batteries.

A SnO/SnO2/GNS composite with controlled oxidation states and composition has been prepared through simple one-pot reduction of an EG suspension of SnCl2 and graphene oxide. The as-prepared composite was characterized by XRD, FT-IR, XPS, SEM, TEM and BET. SnO and SnO2 nanoparticles are uniformly distributed on the surface of the graphene. Taking advantage of the high electron conductivity of graphene and the large theoretical capacity of SnO, this SnO/SnO2/GNS composite exhibits high charge/discharge capacity, good cycling stability and good rate capability. A specific discharge capacity of approximately 464.2 mA h g(-1) is retained after being charged/discharged at a current density of 1000 mA g(-1) for 30 cycles.

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