2,5-Furandicarboxylic acid (FDCA),
an eco-friendly biobased material,
can replace petroleum-based terephthalic acid (TPA), in the polymer
industry, for applications such as water bottle production and food
packaging. In this study, an integrated process was developed for
the coproduction of FDCA as a biobased plastic monomer and 1,5-pentanediol
as a high-value product from lignocellulosic biomass using catalytic
conversions and designing separation areas. The integrated process
has several energy-intensive units that require a considerable amount
of heating sources. Heat integration is performed to reduce and satisfy
total heating requirements. Through a technoeconomic analysis, the
minimum selling price of FDCA is determined to be US$1024/ton. Moreover,
a wide range of sensitivity analyses are conducted to identify the
major cost drivers among the economic and environmental parameters.
Environmental impacts are compared between biomass-derived FDCA and
petroleum-derived TPA productions by life-cycle assessment. In the
former production, fossil depletion is lower (53%) than that of the
latter production, although climate change of the former is higher
(29%) than that of the latter. FDCA production can be more environmentally
friendly by changing the sources for electricity generation.
A cradle-to-gate life cycle assessment provides comprehensive insights into diverse environmental impacts and possible improvements in producing two formic acids.
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