Significant anomalous hydrogeochemical changes in hot spring water are detected during strong seismic cycles. It is now necessary to clarify the relationship between tectonic movements, earthquakes and the evolution of hot springs. In this paper, laboratory analyses of major, trace elements, δD, δ18O and 87Sr/86Sr values of 28 hot spring waters in the Jinshajiang fault zone (JSJFZ) in the northwestern boundary of the Sichuan-Yunnan block were conducted. The results showed that the primary source of water for JSJFZ hot springs was atmospheric precipitation. The geothermal reservoir temperature variation based on the silicon enthalpy mixing model ranged from 73 to 272°C. And the circulation depth range was 1.2–5.4 km. The segmentation characteristics of the 87Sr/86Sr values were related to the influence of source rocks on groundwater cycle processes. A conceptual model of the hydrologic cycle of hot springs explained the spatial distribution of earthquakes associated with tectonic movements. The Batang segment had the strongest water-rock reaction, the highest reservoir temperature and the deepest circulation depth; meanwhile, it was also an earthquake prone area. The fluid circulation of the JSJFZ corresponds well with the seismicity, which indicates that the hydrological characteristics of the hot spring water in a fracture zone play a crucial role in receiving information on seismic activity.

Hydrogeochemical changes in association with earthquakes are considered as a potential means of identifying earthquake precursors. The Xianshuihe fault zone (XSHF) is considered one of the most active seismic fault zones in China; 43 hot springs were sampled and analysed in the laboratory for major elements, silica, stable isotopes (δD and δ18O) and strontium isotopes were investigated from 2008 to 2021. The meteoric water acted as the primary water source of the hot spring in the XSHF, and recharged elevations ranged from 1.9 to 4.8 km. The geothermometers method was used to estimate the region of thermal storage temperature and its temperature between 8 and 142 °C. And the circulation depth ranged from 0.1 to 6.9 km. Most of the hot spring water was immature water with a weak degree of water-rock reaction. However, the degree of water-rock reaction and the depth of hot spring water circulation were high in part of the Kangding and Daufu segments, which also had the highest reservoir temperature and the most frequent strong earthquakes. Temporal variations of hydrogeochemical showed that Na+, Cl− and SO42− decreased obviously following the 12 May 2008 Wenchuan Ms8.0 and existed abnormal value fluctuations from the 20 April 2013 Lushan Ms7.0 to 22 November 2014 Kangding Ms6.3 occurred and after 20 July 2017 returned to the normal levels. And the ion concentrations in hot springs increased by 5% to 35% three months before 22 November 2014 Kangding Ms6.3 with the obvious precursor anomaly. Hydrogeochemical anomalies could be useful for predicting an earthquake in the study area.

Significant hydrogeochemical changes may occur prior- and post-earthquakes. The Xiaojiang fault zone (XJF), situated in a highly deformed area of the southeastern margin of the Tibetan Plateau, is one of the active seismic areas. In this study, major and trace elements, and hydrogen and oxygen isotopes of 28 sites in hot springs along the XJF were investigated from June 2015 to April 2019. The meteoric water acts as the primary water source of the hot spring in the XJF and recharged elevations ranged from 1.8 to 4.5 km. Most of the hot spring water in the study area was immature water and the water–rock reaction degree was weak. The temperature range was inferred from an equation based on the SiO2 concentration and chemical geothermal modeling: 24.3~96.0 °C. The circulation depth for the springs was estimated from 0.45 to 4.04 km. We speculated the meteoric water firstly infiltrated underground and became heated by heat sources, and later circulated to the earth’s surface along the fault and fracture and finally constituted hot spring recharge. Additionally, a continuous monitoring was conducted every three days in the Xundian hot spring since April 2019, and in Panxi and Qujiang hot springs since June 2019. There were short-term (4–35 d) seismic precursor anomalies of the hydrochemical compositions prior to the Xundian ML4.2, Dongchuan ML4.2, and Shuangbai ML5.1 earthquakes. The epicentral distance of anomalous sites ranged from 19.1 to 192.8 km. The anomalous amplitudes were all over 2 times the anomaly threshold. The concentrations of Na+, Cl−, and SO42− are sensitive to the increase of stress in the XJF. Modeling on hydrology cycles of hot springs can provide a plausible physicochemical basis to explain geochemical anomalies in water and the hydrogeochemical anomaly may be useful in future earthquake prediction research of the study area.

The Weixi–Qiaohou Fault (WQF) is considered an important zone of the western boundary of the Sichuan–Yunnan block, and its seismicity has attracted much attention after a series of moderate–strong earthquakes, especially the Yangbi Ms6.4 earthquake that occurred on 21 May 2021. In the present research, we investigate major and trace elements, as well as hydrogen and oxygen isotopes, of 10 hot springs sites located along the WQF, which are recharged by infiltrated precipitation from 1.9 to 3.1 km. The hydrochemical types of most analyzed geothermal waters are HCO3SO4-Na, SO4Cl-NaCa, and SO4-Ca, proving that they are composed of immature water and thus are characterized by weak water–rock reactions. The heat storage temperature range was from 44.1 °C to 101.1 °C; the circulation depth was estimated to range between 1.4 and 4.3 km. The results of annual data analysis showed that Na+, Cl−, and SO42− in hot springs decreased by 11.20% to 23.80% north of the Yangbi Ms5.1 earthquake, which occurred on 27 March 2017, but increased by 5.0% to 28.45% to the south; this might be correlated with the difference in seismicity within the fault zone. The results of continuous measurements of NJ (H1) and EYXX (H2) showed irregular variation anomalies 20 days before the Yangbi Ms6.4 earthquake. In addition, Cl− concentration is more sensitive to near-field seismicity with respect to Na+ and SO42−. We finally obtained a conceptual model on the origin of groundwater and the hydrogeochemical cycling process in the WQF. The results suggest that anomalies in the water chemistry of hot spring water can be used as a valid indicator of earthquake precursors.

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