The Fukushima nuclear accident has highlighted the importance of finding a better final storage method for radioactive cesium species. Cs is highly soluble in water, and can easily exchange with other alkali ions in zeolites or clays to form stable complexes. However, Cs+ is released from Cs+ complexes into water when surrounded by an excess of water. Pollucite may be the best final storage option for Cs+, but its typical synthesis requires heating to about 1200°C in air. Here, we show that the hydrothermal synthesis of pollucite can be completed at 300°C in three hours from any zeolite or clay. Furthermore, our procedure does not require ion exchange before synthesis. Radioactive Cs is usually found in complexes with clays. At that time, this method only requires calcium hydroxide, water, and three hours of hydrothermal synthesis, so the process is both inexpensive and practical for large-scale application. Pollucite is an analog of analcime zeolite, and contains a channel system 2.8 Å in diameter, which is formed by 6-oxygen rings. As the diameter of Cs+ is 3.34 Å and each Cs+ exists independently within a separate portion of the channel, Cs+ cannot exit the pollucite framework without breaking it.
Liquid-crystal displays (LCDs) are used for displaying medical images under various illuminance conditions and with ambient-lighting colors. Our purpose in this study was to understand the variations of the chromaticity in LCDs under different fluorescent lighting conditions. The variation of chromaticity of LCDs at a white point consisting of equivalent pixel value in Red, Green, and Blue was examined under different types of fluorescent lighting. The direction of changes in the chromaticity diagram shifted to the color of each fluorescent lighting. When the differences in chromaticity (∆u'v') increased, the observers' confidence levels in distinguishing color differences also increased. When the luminance of the LCD increased, observers' sensitivities for recognizing differences in chromaticity also increased as compared to observers' sensitivities at lower luminances. Our results indicate that observers recognized slightly yellowish colors even if ∆u'v' was less than 0.01; thus, observers could perceive differences in chromaticity. These results could provide important and relevant information with regard to better ambient lighting conditions in an image-reading room.
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