Air pollution induced by pathogenic particulate matter
(PM) has
posed a serious threat to public health worldwide. Advanced air filters
are thus required, not only exhibiting high PM capture efficiency,
low breathing resistance, and high internal moisture transferring
performance but also isolating and inactivating external pathogenic
aerosols. In this study, we demonstrated a facile approach to construct
a biomimetic fibrous leaf-vein membrane with unidirectional water
penetration and effective antibacterial PM filtration by one-step
electrospinning of poly(vinylidene fluoride) (PVDF)-based multilayer
nanofibers. With ultrathin fibers penetrating the skeletal framework
of bimodal thick fibers, the membranes showed gradient interconnected
porous structures and achieved a highly efficient and stable (in an
acid and alkali environment) PM0.3 interception (>99.98%)
with low air drag (51–71 Pa). In addition, the gradient narrow
pores of the membranes contributed to a gradient higher hydrophilicity.
The subsequent unidirectional water motion effectively isolates pathogenic
aerosols typically generated by external individuals or ultrafast
water penetration from the inverse face. Moreover, the membranes demonstrated
an antibacterial efficacy (>99.99%) in a 5 min contact, inactivating
the intercepted airborne pathogens efficiently. The test results proved
that the proposed membranes were promising advanced air filters for
respirator applications.
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