Nanostructured conductive polymer hydrogels (CPHs) have been extensively applied in energy storage owing to their advantageous features, such as excellent electrochemical activity and relatively high electrical conductivity, yet the fabrication of self-standing and flexible electrode-based CPHs is still hampered by their limited mechanical properties. Herein, macromolecularly interconnected 3D graphene/nanostructured CPH is synthesized via self-assembly of CPHs and graphene oxide macrostructures. The 3D hybrid hydrogel shows uniform interconnectivity and enhanced mechanical properties due to the strong macromolecular interaction between the CPHs and graphene, thus greatly reducing aggregation in the fiber-shaping process. A proof-of-concept all-gel-state fibrous supercapacitor based on the 3D polyaniline/graphene hydrogel is fabricated to demonstrate the outstanding flexibility and mouldability, as well as superior electrochemical properties enabled by this 3D hybrid hydrogel design. The proposed device can achieve a large strain (up to ≈40%), and deliver a remarkable volumetric energy density of 8.80 mWh cm (at power density of 30.77 mW cm ), outperforming many fiber-shaped supercapacitors reported previously. The all-hydrogel design opens up opportunities in the fabrication of next-generation wearable and portable electronics.

No abstract

Abstract-This paper studies the binary hypothesis test of detecting the presence or absence of a target in a highly cluttered environment by using time reversal. In time reversal, the backscatter of a signal transmitted into a scattering environment is recorded, delayed, energy normalized, and retransmitted through the medium. We consider two versions of the test-target channel frequency response assumed known or unknown-and, for each version, contrast two approaches: conventional detection (where no time reversal occurs) and time reversal detection. This leads to four alternative formulations for which we derive the optimal detector and the generalized likelihood ratio test, when the target channel frequency response is known or unknown, respectively. We derive analytical expressions for the error probabilities and the threshold for all detectors, with the exception of the time reversal generalized likelihood ratio test. Experiments with real-world electromagnetic data for two channels (free space with a target immersed in 20 scatterers and a duct channel) confirm the analytical results and show that time reversal detection provides significant gains over conventional detection. This gain is explained by the empirical distribution or type of the target channel frequency response-richer scattering channels induce types with heavier tails and larger time reversal detection gains.

No abstract

No abstract