A simple, rapid, and environmentally friendly method has been established for the determination of chlorpyrifos residue in green tea by dispersive liquid-liquid microextraction(DLLME) and gas chromatography-flame photometric detection (GC-FPD). Some experimental parameters that influence extraction efficiency, such as the kind and volume of disperser solvents and extraction solvents, extraction time, addition of salt and pH, were investigated. And the optimal experimental conditions were obtained, quantitative analysis was carried out using external standard method. The correlation coefficient of the calibration curves was 0.999 with in 0.05mg/kg to 5 mg/kg. The results showed that under the optimum conditions，the enrichment factors of the chlorpyrifos was about 484, the recoveries for standard addition fell in the range from 91.94% to 104.70% and the relative standard deviations (RSD) was 4.61%. The limit of quantification (LOQ) of chlorpyrifos in green tea was 0.02μg/ml at the signal/noise (S/N) ratio of 3.