A reduced graphene oxide coating was deposited on a titanium substrate for potential anti-friction applications in nano- or micro-mechanical systems. A γ-aminopropyltriethoxysilane coating was self-assembled on the substrate as an adhesive interlayer beforehand. The process parameters of self-assembly and hydrothermal reduction of graphene oxide coating were explored via water contact angle and tribological tests. Insufficient self-assembly duration of graphene oxide layer can be detected by water contact angle results, and the corresponding coating displayed a higher coefficient of friction and shorter anti-wear lifetime than the optimized one. Proper hydrothermal temperature and duration were also confirmed by its water contact angle, coefficient of friction and anti-wear lifetime. Noticeably, excessive hydrothermal temperature or duration would reduce the coefficient of friction, but diminish the anti-wear resistance. The optimized process parameters were confirmed as assembly duration of graphene oxide coating for 12 h, hydrothermal reduction duration of 6–8 h at 135 °C. Nano tribological behaviors of the obtained hydrothermal reduced graphene oxide coating by AFM tester were then investigated under various testing circumstances. The results showed that the coating performed reliable and low adhesion and friction forces under all circumstances. The nanowear resistance of the titanium substrate was significantly strengthened by the prepared coating.
Reinforced cushion and pile are two important components of the geosynthetic-reinforced and pile-supported (GRPS) composite foundation. Studies on the traditional GRPS composite foundation with uniform section piles have compared the performance of GRPS before and after the reinforcement of cushion yet neglects the effects of reinforcement type and pile shape on this composite foundation. To address this problem, the geosynthetic-reinforced and tapered pile-supported (GRTPS) composite foundation with section-variable piles was proposed in this study as a new form of the GRPS composite foundation. The settlement of the proposed composite foundation and the stress distribution on piles and soil under three cushion conditions (gravel cushion (GC), geogrid-reinforced cushion (GGRC), and geocell-reinforced cushion (GCRC)) were analyzed through a static test by using three models of specimens with nine piles. Test results demonstrate that under the test load, the pile-soil settlement differences under GGRC and GCRC are 43.4% to 49.8% and 34.7% to 39.8% of that under GC. Meanwhile, the pile-soil stress ratios under GGRC and GCRC are 1.47 to 1.88 and 1.77 to 2.08 times of that under GC. The reinforced cushion can effectively reduce the settlement of the composite foundation and the pile-soil settlement difference, increase the pile-soil stress ratio, and relieve stress concentration in some piles. GCRC can improve the performance of the GRTPS composite foundation more effectively than GGRC under the same conditions. No negative friction region is observed on the upper piles in the GRTPS composite foundation. The tapered piles are better than the uniform section ones as well as can increase the bearing capacity and decrease the settlement of the composite foundation. The findings of this work can provide references for the engineering design and application of the GRTPS composite foundation.
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