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Room-temperature Li/Na-S batteries are promising energy storage solutions, but unfortunately suffered from serious cycling problems rooted in their polysulfide intermediates.Conventional strategy to tackle with this issue is to design host materials for trapping polysulfides via weak physical confinement and interfacial chemical interactions. Even though beneficial, their capability for the polysulfide immobilization is still limited. Herein, we revisit the unique sulfiphilic nature of metallic Cu. Upon the exposure to polysulfide in aqueous or aprotic solution, the surface sulfidization rapidly took place, resulting in the formation of Cu 2 S nanoflake arrays with tunable This article is protected by copyright. All rights reserved. 2 texture. When sulfidized Cu current collector is directly used as the sulfur-equivalent cathode, it enables high-performance Li/Na-S batteries at room temperature with reasonable high sulfur loading. Specific capacities up to ~1200 mAh g −1 for Li-S and ~400 mAh g −1 for Na-S are measured when normalized to the amount of equivalent sulfur, and can be readily sustained for >1000 cycles.

Mesoporous SnO2 nanosheets from the self-templated synthesis enables active and selective CO2 reduction to formate.

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