We analyze the mechanism for industrial co-agglomeration in Chinese 283 cities to affect haze pollution from 2003 to 2016 and examine the possible mediating effects of urbanization and energy structure between haze pollution and industrial co-agglomeration, finally obtaining the following results. First, industrial co-agglomeration and haze pollution across China, including central and eastern regions keep a typical inverted U-shaped curve relationship. That is, industrial co-agglomeration first promotes haze pollution and then restrains it. However, the impact of industrial co-agglomeration on haze pollution in western China is still on the left side of the inverted U-shaped curve, reflecting a promotion effect. Second, industrial co-agglomeration has a significant spatial spillover effect on haze pollution. Additionally, industrial co-agglomeration can promote haze pollution in local regions but inhibit it in surrounding regions in both the short and long run. In contrast, when the industrial co-agglomeration index exceeds the inflection point (3.6531), it benefits the reduction of haze pollution in local regions, while not being conducive to it in the neighboring regions. Third, industrial co-agglomeration can affect haze pollution through urbanization and energy structure, that is, urbanization and energy structure play an intermediary role between them.

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