Understanding the growth behaviour of an aluminosilicate sol during ageing is necessary for the design of the sol and the synthesis of NaY zeolite. Herein, aluminosilicate sols with three different SiO 2 /Al 2 O 3 ratios were prepared and aged for varying times at 293 K. The sol was then introduced as a structuredirecting agent in the feedstock gel to generate NaY zeolite. The structure evolution of the sol species during the ageing process was studied by in situ small-angle X-ray scattering (SAXS) using synchrotron radiation. SAXS data, in combination with transmission electron microscopy images, Raman spectra and X-ray diffraction patterns, present a detailed description of the sol species, revealing an interplay between the fractal structure and reactivity to generate NaY zeolite. The SiO 2 /Al 2 O 3 ratios in the sol play a critical role in the structure evolution of the aluminosilicate species during the ageing, particularly with respect to their size distributions and the fractal dimensions. The species with suitable size and compactness in the sol are found to be an active precursor for achieving a highly crystalline NaY zeolite. The sol with an SiO 2 /Al 2 O 3 ratio of 20 possesses active species with a mass fractal dimension D m of 2.0-2.6 after ageing, which leads to the formation of a well crystallized NaY zeolite. However, the high-silica sol-25, with an SiO 2 /Al 2 O 3 ratio of 25, and alumina rich sol-10, with a ratio of 10, experience growth at either slow or fast rates. In these cases the active species have smaller D m (1.1-1.9) or larger D m (2.6-2.8), respectively, displaying low/poor activity to generate NaY zeolite. The mechanisms regulating the growth behaviour of the sols during ageing are proposed.

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ZSM-5 by EtOH, possessing an ultra-high Brønsted/Lewis acidity ratio, has a long lifetime and suppresses coke deposit during n-hexane cracking.

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Hierarchical Al-ZSM-5@B-ZSM-5 core–shell zeolite was prepared to boost turnover number of MTP reaction.