The oxygen evolution reaction (OER) is pivotally involved in proton exchange membrane water electrolyzers (PEMWEs). However, the commercialized iridium‐based catalysts often suffer from severe sluggish kinetics, eventually deteriorating the polarization and overall PEMWEs performance. Therefore, to develop OER electrocatalysts with promising reaction kinetics and high stability is of great significance for PEMWEs. Compared to iridium, the ruthenium‐based catalysts possess lower price and higher activity in acidic water oxidation, which promises Ru‐based materials to replace the state‐of‐the‐art IrOx. Yet, the less stable ruthenium than iridium impedes its real applications. In this mini review, recent knowledge of feasible engineering strategies for migrating the Ru‐based electrocatalysts' stability is summarized. In order to improve performance and durability, basic fundamentals of acidic OER on nanoscale and molecular engineered Ru‐based electrocatalysts are briefly introduced. In the end, the challenges and outlook for engineering novel Ru‐based electrocatalysts are presented.
A novel titanium, nitrogen co-doped carbon material was designed via a one-step solvothermal reaction at a moderate temperature. Characterizations with scanning electron microscopy and transmission electron microscopy illustrate that carbon...
To improve the properties of fluororubber (FKM), aminated carbon nanotubes (CNTs-NH2) and acidified carbon nanotubes (CNTs-COOH) were introduced to modulate the interfacial interactions in FKM composites. The effects of chemical binding and F–H polar interactions between CNTs-NH2, CNTs-COOH, and FKM on the mechanical, electrical, thermal, and wear properties of the FKM composites were systematically investigated. Compared to the pristine FKM, the tensile strength, modulus at 100% strain, hardness, thermal conductivity, carbon residue rate, and electrical conductivity of CNTs-NH2/CNTs-COOH/FKM were increased by 112.2%, 587.5%, 44.2%, 37.0%, 293.5%, and nine orders of magnitude, respectively. In addition, the wear volume of CNTs-NH2/CNTs-COOH/FKM was reduced by 29.9%. This method provides a new and effective way to develop and design high-performance fluororubber composites.
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