We succeeded in the development of two facile synthetic methods of carbon nanotubes (CNTs) by using a domestic microwave oven and a commercially available small microwave furnace from Art Box™. Our handmade apparatus was cheap and the synthesis of the CNTs took only 5 min. Interestingly, we could selectively synthesize the magnetic nickel-containing CNTs and non-magnetic nickel-free CNTs by our two developed methods.
The dispersion of carbon nanotubes is a key issue for maximizing their performance in many applications. Here we describe the design and synthesis of an efficient dispersant for the so-called “super-growth” single-walled carbon nanotubes (SG-SWNTs) to provide a stable and homogeneous dispersion in typical organic solvents simply by sonication. The synthesized dispersant is a copolymer composed of a naphthalene diimide and poly(dimethylsiloxane), and the dispersions were characterized using visible absorption, Raman, AFM, and TGA measurements as well as molecular-mechanics simulations. It was found that the copolymer efficiently dissolves the SG-SWNTs in many solvents including methyl ethyl ketone, methyl isobutyl ketone, and toluene that are widely-used solvents in polymer/resin-related industrial areas.
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