Solution blowing (SB) is a promising and scalable approach for the production of nanofibers. Air pressure, solution flowrate, and nozzle-collector distance were determined as effective process parameters, while solution concentration was also reported as a material parameter. Here we performed a parametric study on thermoplastic polyurethane/dimethyl formamide (TPU/DMF) solutions to examine the effect of such parameters on the resultant properties such as fiber diameter, diameter distribution, porosity, and air permeability of the nanofibrous webs. The obtained solution blown thermoplastic polyurethane (TPU) nanofibers had average diameter down to 170 6 112 nm, which is similar to that observed in electrospinning. However, the production rate per nozzle can be 20 times larger, which is primarily dependent on air pressure and solution flow rate (20 mL/h). Moreover, it was even possible to produce nanofibers polymer concentrations of 20%; however, this increased the average nanofiber diameter. The fibers produced from the TPU/DMF solutions at concentrations of 20% and 10% had average diameters of 671 6 136 nm and 170 6 112 nm, respectively. SB can potentially be used for the industrial-scale production of products such as nanofibrous filters, protective textiles, scaffolds, wound dressings, and battery components.
A large surface area, scalable porosity, and versatility have made nanofibres one of the most widely investigated morphologies among the nanomaterials.
Present study deals the surface morphology and structural composition analysis of alkali (NaOH) treated 2.5% 5.0% and 7.5 wt% Ensete stem fiber obtained from the Ethiopian Ensete ventricosum plant. Treated Ensete fibers reinforced unsaturated polyester (UP) composites were characterized in terms of tensile, flexural, surface morphology and dynamic mechanical properties. Mechanical test results revealed that 5.0 wt% alkali treated Ensete fibers/UP composites showed 14.5% and 43.5% increase in flexural strength and Young's modulus respectively, with relative to untreated Ensete fibers/UP composites. Storage and loss modulus value also highest for 5.0 wt% alkali treated Ensete fibers/UP composites. Moreover, a positive shift in glass transition temperature (Tg) of composites after alkali treatment and tensile fracture surface morphology indicates better interfacial interaction in treated Ensete fibers/UP composites. Overall we concluded that 5.0 wt% treated Ensete fibers satisfactorily and effectively improved mechanical, morphological and dynamic properties of UP for various engineered and hi-tech applications.
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