The relation between germanium monoxide (GeO) desorption and either improvement or deterioration in electrical characteristics of metalGeO(2)Ge capacitors fabricated by thermal oxidation has been investigated. In the metalGeO(2)Ge stack, two processes of GeO desorption at different sites and at different temperatures were observed by thermal desorption spectroscopy measurements. The electrical characteristics of as-oxidized metalGeO(2)Ge capacitors shows a large flat-band voltage shift and minority carrier generation due to the GeO desorption from the GeO(2)Ge interface during oxidation of Ge substrates. On the other hand, the electrical properties were drastically improved by a postmetallization annealing at low temperature resulting in a metal catalyzed GeO desorption from the top interface.

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This paper addresses the opportunities and challenges of wet and dry selective etches in the integration of gate-all-around (GAA) field-effect transistor (FET), which is emerging as a promising solution to replace FinFET for the advanced logic devices. For the GAA device fabrication, a quintessential challenge is a controlled isotropic etching of dielectrics, semiconductors, and metals with high selectivity to the exposed materials. In this paper, the significance of the unit process modules in the GAA device integration: shallow trench isolation (STI), inner spacer formation, replacement metal gate (RMG) and self-aligned interconnect in the middle-of-line (MOL) and the back-end-of-line (BEOL), will be discussed.

The nature of the anomalous positive charge present in thermally grown germanium dioxide film as well as its generation mechanism have been investigated. Flat-band voltage shift due to the positive charge, which can be generated at a given electric field, increases linearly with the maximum field in the oxide. Moreover, the density of the positive charge strongly depends on the amount of water molecules in the oxide. It was found that the positive charge is reduced by anneal process due to water desorption from the oxide film.

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