ICN (Information Centric Networking) has received much attention due to its built-in functionalities such as caching and mobility-support. One of the important research challenges is to reduce the power consumed by ICN networks because ICN's packet forwarding and packet-level caching are power-hungry. As the first step to achieve power-efficient ICN networks, this paper develops a power consumption model of a multicore software ICN router while taking into account the power consumed by power-hungry computation. This paper makes the following three contributions: First, the model is one of the first realistic models which consider ICN packet forwarding and packet-level caching. Second, the model is represented as a concise set of equations with just a few parameters. Third, we apply the model to estimate power consumed by simple networks.
Positional isomers of naturally occurring peptide subunits were synthesized via highly diastereoselective reduction of tert-butylsulfinyl ketimines as a key reaction. While NaBH reduction of ketimines derived from 2-thiazolyl ketones afforded the (R,R)-isomer with moderate diastereoselectivity, L-Selectride reduction afforded the (R,S)-isomer as the sole product. In contrast, ketimines derived from tert-butyl 2-thiazolyl ketone afforded the (R,R)-isomer with low diastereoselectivity by both NaBH and L-Selectride reduction. Stereochemistry of the reaction was discussed based on calculation of the conformational energies for ketimines.
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